自蔓延高温合成陶瓷内衬油管的力学和耐腐蚀性能分析

管西巧; 肖凤艳; 黄智; 谢维涛; 王守泽; 魏世丞

doi:10.3981/j.issn.1000-7857.2023.08.01261

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科技导报 ›› 2024, Vol. 42 ›› Issue (23) : 108-118. DOI: 10.3981/j.issn.1000-7857.2023.08.01261

论文

自蔓延高温合成陶瓷内衬油管的力学和耐腐蚀性能分析

作者信息 -

1. 烟台职业学院智能制造系, 烟台 264670;
2. 中山职业技术学院机电工程学院, 中山 528400;
3. 中国石油长庆油田分公司第九采油厂, 银川 721000;
4. 吉林省大多天盛金属陶瓷技术有限公司, 松原 138000;
5. 陆军装甲兵学院再制造技术国防科技重点实验室, 北京 100072

作者简介:

管西巧，讲师，研究方向为机械制造，电子信箱：qiao19880828@163.com

Mechanical and corrosion resistance analysis of self-propagating high-temperature synthetic ceramic lined oil pipes

Author information -

1. Department of Intelligent Manufacturing, Yantai Vocational College, Yantai 264670, China;
2. Department of Mechanical and Electrical Engineering, Zhongshan Polytechnic, Zhongshan 528400, China;
3. China Petroleum Changqing Oilfield Branch Ninth Oil Production Plant, Yinchuan 721000, China;
4. Jilin Province, Most Tiansheng Metal Ceramics Technolog Co., Ltd., Songyuan 138000, China;
5. Key Laboratory of Remanufacturing Technology for National Defense Science and Technology, Army Armored Forces College, Beijing 100072, China

摘要

为提升油田开发用油管的使用服役性能，以Ф73×5.51 mm J55油管为基体，运用自蔓延高温合成技术（SHS）在 Al+Fe₂O₃ 基本铝热体系中（B 组分）添加质量分数为 4%Nb₂O₅、8%ZrO₂、13%CrO₃、5%SiO₂为新型 SHS 材料体系，制备了新型陶瓷内衬耐磨涂层油管（A 组分）。运用SEM、EDS、XRD、FTIR等分析手段测试了耐酸性腐蚀、结合强度、弯曲强度和压溃强度等性能，对比分析结果表明：A组分制备的陶瓷内衬层的耐腐蚀性、弯曲强度、结合强度及压溃强度均优于 B。其中，A 组分涂层和 B 组分涂层 1200 h 的流动腐蚀失重率分别为0.42%、0.54%，性能均优于 J55油管基体。A 组分制备的陶瓷内衬油管弯曲强度比 B 组分提升了15.9%。基于滑脱位置观测，确定了Fe-Fe界面部分冶金结合力与Fe-Al₂O₃界面机械结合力强弱的转换温度约为 200℃，低温时机械结合力大于冶金结合力，高温时机械结合力小于冶金结合力。

Abstract

In order to improve the service performance of oil pipeline for oilfield development, this paper takes Ф73×5.51 mm J55 oil pipeline as the substrate, and uses self-spreading high-temperature synthesis technology (SHS) to add 4wt%Nb₂O₅, 8wt% ZrO 2, 13wt% CrO₃, and 5wt% SiO₂ to the basic aluminum thermal system of Al+Fe₂O₃ (B component) as a new type of SHS material system, and prepares a new type of ceramic lined wear-resistant coated oil pipe (A component). Using SEM analysis, EDS analysis, XRD analysis, FTIR analysis and other analytical means to test the acid corrosion resistance, bonding strength, bending strength and crush strength and other properties, comparative analysis results show that: the corrosion resistance, bending strength, bonding strength and crushing strength of the ceramic lining layer prepared by component A are better than that of component B. The flow corrosion weight loss rate of component A coating and component B coating at 1200 h is 0.42% and 0.54%, respectively, which is better than that of J55 tubing substrate, and the bending strength of ceramic lined tubing prepared by component A is 15.9% higher than that of component B. Based on the observation of the slip position, the transition temperature between the strength of partial metallurgical bonding at the Fe-Fe interface and the mechanical bonding at the FeAl₂O₃ interface was determined to be about 200℃, with the mechanical bonding strength being greater than the metallurgical bonding strength at low temperatures, and the mechanical bonding strength being less than the metallurgical bonding strength at high temperatures. Both the bond strength and the crush strength properties of the ceramic lining layer showed a significant decreasing trend with increasing temperature.

导出引用

管西巧, 肖凤艳, 黄智, 谢维涛, 王守泽, 魏世丞. 自蔓延高温合成陶瓷内衬油管的力学和耐腐蚀性能分析[J]. 科技导报, 2024, 42(23): 108-118 https://doi.org/10.3981/j.issn.1000-7857.2023.08.01261

GUAN Xiqiao, XIAO Fengyan, HUANG Zhi, XIE Weitao, WANG Shouze, WEI Shicheng. Mechanical and corrosion resistance analysis of self-propagating high-temperature synthetic ceramic lined oil pipes[J]. Science & Technology Review, 2024, 42(23): 108-118 https://doi.org/10.3981/j.issn.1000-7857.2023.08.01261

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