To prepare a novel polyaniline conductive composite, nanocellulose reinforced polyaniline conductive composites were prepared using the method of in situ polymerization, where hydrochloric acid was used as the doping agent, and ammonium persulfate as the oxidant. The chemical composition, microstructure, electrical conductivity and mechanical properties of the composite were tested by fourier transform infrared spectroscopy, scanning electron microscopy, a four-probe tester and a universal mechanical testing machine. The results show that when the mass fraction of polyaniline reached 20%, the composite of nanocellulose reinforced polyaniline maintained good electrical conductivity and improved toughness.
[1] 吕秋丰, 李新贵, 黄美荣. 聚苯胺-聚合物纳米复合材料的制备及应用[J]. 郑州大学学报: 理学版, 2004, 36(4): 74-78. Lü Qiufeng, Li Xingui, Huang Meirong. Preparation and application of polyaniline polyanilinepolymer nanocomposites[J]. Zhengzhou University: Natural Science, 2004, 36(4): 74-78.
[2] 卢芸, 孙庆丰, 李坚. 高频超声法纳米纤丝化纤维素的制备与表征[J]. 科技导报, 2013, 31(15): 17-22. Lu Yun, Sun Qingfeng, Li Jian. Preparation and characterization of nanometer high-frequency ultrasound of cellulose fibrils[J]. Science & Technology Review, 2013, 31(15): 17-22.
[3] 张鸿, 王立久. 聚苯胺/聚丙烯复合导电纤维的结构与性能[J]. 高分子 材料科学与工程, 2008, 24(6): 132-135. Zhang Hong, Wang Lijiu. Structure and properties of Polyanilinepolypropylene composite conductive fiber[J]. High Polymer Materials Science and Engineering, 2008, 24(6): 132-135.
[4] 陈砺, 邓丽华, 严宗诚, 等. 木质纤维素水解制化学品的研究进展[J]. 科技导报, 2011, 29(34): 68-72. Chen Li, Deng Lihua, Yan Zongcheng, et al. Research progress of lignocellulose hydrolysis of chemicals[J]. Science & Technology Review, 2011, 29(34): 68-72.
[5] 高洁, 汤烈贵. 纤维素科学[M]. 北京: 科学出版社, 1999: 173. Gao Jie, Tang Liegui. Cellulose science [M]. Beijing: Science Press, 1999: 173.
[6] 赵艳峰. 纤维素的改性技术及进展[J]. 天津化工, 2006, 20(2):11-14. Zhao Yanfeng. Advances in technology and modified cellulose[J]. Journal of Chemical Industry in Tianjin, 2006, 20(2): 11-14.
[7] Bai H, Chen Q, Li C, et al. Electrosynthesis of polypyrrole/sulfonated PANI composite films and their applications for ammonia gas sensing[J]. Polymer, 2007, 48(14): 4015-4016.
[8] Zhang L X, Zhang L J, Wan M X, et al. Polyaniline micro/nanofibers doped with saturation fatty acids[J]. Synthetic Metals, 2006, 156(5-6): 454–458.
[9] Razak S I A, Rahman W A W A, Hashim S, et al. In situ surface modification of natural fiber by conducting polyaniline[J]. Composite Interfaces, 2012, 19(6): 365-376.
[10] Park M, Cheng J, Shin S, et al. Flexible nanocomposite membrane of bacterial cellulose/polyaniline[J]. Procedia Engineering, 2012, 44(7): 863-865.
[11] Müller D, Mandelli J S, Marins J A, et al. Electrically conducting nanocomposites: Preparation and properties of polyaniline (PAni)- coated bacterial cellulose nanofibers (BC)[J]. Cellulose, 2012, 19(5): 1645-1654.
[12] Kalluri S, Madhavan A A, Bhupathi P A, et al. Electrical properties of electrospun polyaniline-carbon black composite nanofibers[J]. Science of Advanced Materials, 2012, 4(12): 1220-1225.
[13] Wang H, Zhang P, Zhang W, et al. Electrodeposition and characterization of polyaniline film[J]. Chemical Research in Chinese Universities, 2012, 28(1): 111-136.
[14] Zang J, Wang Y, Zhao X, et al. Electrochemical synthesis of polyaniline on nanodiamond powder[J]. International Journal of Electrochemical Science, 2012, 7(2): 1677-1687.
[15] Chao L, Ho K S, Shen S Y, et al. Short polyaniline nanorod prepared in the presence of para- phenylenediamine[J]. Journal of Applied Polymer Science, 2013, 127(3): 1853-1862.
[16] Muthukumar N, Thilagavathi G. Development and characterization of electrically conductive polyaniline coated fabrics[J]. Indian Journal of Chemical Technology, 2012, 19(6): 434-441.
[17] Jin Y, Chen H Y, Chen M H, et al. Carbon nanotube/polyaniline/ graphene composite paper and its electrochemical capacitance behaviors[J]. Acta Physico-Chimica Sinica, 2012, 28(3): 609-614.
[18] 徐惠, 李俊玲, 彭振军. 聚苯胺防腐涂料研究进展[J]. 化学研究, 2013, 24(2): 195-198. Xu Hui, Li Junling, Peng Zhenjun. Advances in anti-corrosion coating of polyaniline[J]. Chemical Research, 2013, 24(2): 195-198.
[19] 王香琴, 辛斌杰, 许鉴. 导电聚苯胺的制备及其表征[J]. 材料导报, 2013, 27(16): 46-53. Wang Xiangqin, Xin Binjie, Xu Jian. Preparation and characterization of conductive polyaniline[J]. Materials Review, 2013, 27(16): 46-53.
[20] 袁冰清, 郁黎明, 盛雷梅, 等. 石墨烯/聚苯胺复合材料的电磁屏蔽性 能[J]. 复合材料学报, 2013, 30(1): 22-26. Yuan Bingqing, Yu Liming, Sheng Leimei, et al. Electromagnetic shielding properties of graphene/polyaniline composites[J]. Acta Materiae Compositae Sinica, 2013, 30(1): 22-26.
[21] 孙通, 李晓霞, 郭宇翔, 等. 不同酸掺杂聚苯胺的电化学聚合及性能[J]. 化工进展, 2013(8): 1870-1875. Sun Tong, Li Xiaoxia, Guo Yuxiang, et al. Electrochemical polymerization and properties of polyaniline doped with different acids[J]. Chemical Engineering Progress, 2013(8): 1870-1875.