专题论文

双金属柱撑蒙脱石制备及应用研究进展

  • 主曦曦 ,
  • 王力
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  • 山东科技大学化学与环境工程学院, 青岛266590
主曦曦,博士研究生,研究方向为矿物材料的制备和应用,电子信箱:zhuxixi1986@126.com

收稿日期: 2013-12-13

  修回日期: 2013-12-27

  网络出版日期: 2014-04-10

基金资助

国家自然科学基金项目(21276146)

Preparation and Application of Bi-metal Pillared Montmorillonite

  • ZHU Xixi ,
  • WANG Li
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  • College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China

Received date: 2013-12-13

  Revised date: 2013-12-27

  Online published: 2014-04-10

摘要

双金属柱撑蒙脱石在吸附、催化领域具有广阔的应用前景。综述了近年来双金属柱撑蒙脱石制备过程中柱化剂制备、柱撑方法及其在催化和吸附领域的应用,指出制备周期较长、热稳定性和水热稳定性不高、孔径分布不均等是目前双金属柱撑蒙脱石研究中存在的主要问题。今后研究中,采用多金属柱撑,引入稀土金属,探究柱撑机制,分析结构与性能的关系,制备高性能、多功能蒙脱石材料将成为主要方向。

本文引用格式

主曦曦 , 王力 . 双金属柱撑蒙脱石制备及应用研究进展[J]. 科技导报, 2014 , 32(9) : 67 -70 . DOI: 10.3981/j.issn.1000-7857.2014.09.010

Abstract

The bi- metal pillared montmorillonite is an important type of the pillared montmorillonite. It has application prospects in both adsorption and catalysis. This paper reviews the preparation of the pillaring agent, the approach of the pillared montmorillonite as well as the application in catalysis and adsorption. The long preparation period, the unsatisfactory thermal and hydrothermal stability and the uneven distribution of pores are the major problems. In future studies, the multimetal pillared structure or the introduction of rare earth metals, the mechanism, the retationship between structure and properties and the preparation of high-performance, multifunctional montmorillonite materials are the main subjects.

参考文献

[1] 姜桂兰, 张培萍. 膨润土加工与应用[M]. 北京: 化学工业出版社, 2005: 2-3. Jiang Guilan, Zhang Peiping. Processing and application of bentonite[M]. Beijing: Chemica Industry Press, 2005: 2-3.
[2] 吴平宵, 张惠芬, 郭九皋. 羟基铁铝柱撑蒙脱石Keggin结构的稳定性[J]. 矿物学报, 1999, 19(2): 132-138. Wu Pingxiao, Zhang Huifen, Guo Jiugao. The stability of keggin structure in hydroxyl-Fe-Al pillared montmorillonite[J]. Acta Mineralogica Sinica, 1999, 19(2): 132- 138.
[3] 刘灵燕, 肖金凯, 张澄博, 等. 柱化剂研究进展[J]. 矿物岩石地球化学 通报, 2002, 21(4): 247-252. Liu Lingyan, Xiao Jinkai, Zhang Chengbo, et al. Review of research on pillaring species[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2002, 21(4): 247-252.
[4] Mujde A, Saadet Y. Effect of OH-/Al3+ and Al3+/clay ratio on the adsorption properties of Al-pillared bentonites[J]. Colloids and Surfaces A: Physicochemical and Engineer Aspects, 2007, 306: 88-94.
[5] 肖子敬, 戴劲草, 叶玲. 铬簇合物及铬铝交联蒙脱石纳米复合材料的 形成[J]. 无机材料学报, 2003, 18(2): 379-384. Xiao Zijing, Dai Jingcao, Ye Ling. Formation of cross-linking montmorillonite nanocomposites by adopting chromium compound[J]. Journal of Inorganic Materials, 2003, 18(2): 379-384.
[6] Jurate V, Rajender S V. Photoinduced catalytic adsorption of model contaminants on Bi/Cu pillared montmorillonite in the visible light range[J]. Separation and Purification Technology, 2011, 78: 201-207.
[7] 曹明礼, 于阳辉, 袁继祖, 等. Al-Mn柱撑粘土的制备和微结构变化研 究[J]. 硅酸盐学报, 2002, 30(1): 86-90. Cao Mingli, Yu Yanghui, Yuan Jizu. Preparation and microstructure of Al-Mn pillared interlayer montmorillonite[J]. Journal of the Chinese Ceramic Society, 2002, 30(1): 86-90.
[8] 管俊芳, 狄敬茹, 于吉顺, 等. Zr/Al基柱撑蒙脱石矿物材料的红外光 谱研究[J]. 硅酸盐学报, 2005, 33(2): 220-224. Guan Junfang, Di Jingru, Yu Jishun, et al. Infrared spectra of Zr/Al pillared montmorillonite mineral material[J]. Journal of the Chinese Ceramic Society, 2005, 33(2): 220-224.
[9] 丁述理, 彭苏萍, 刘钦甫. La-Al柱撑蒙脱石的超声制备及热稳定性 研究[J]. 中国矿业大学学报, 2003, 32(5): 496-499. Ding Shuli, Peng Suping, Liu Qinfu. Preparation and thermal stability of La-Al pillared montmorillonite prepared by power ultrasonic treatment[J]. Journal of China University of Mining & Technology, 2003, 32(5): 496-499.
[10] Mikhail S, Tatjana S, Michal R, et al. Characterization of the microporosity of chromia-and titania-pillared montmorillonites differing in pillar density[J]. Microporous and Mesoporous Materials, 2000, 37: 187-200.
[11] Mandalia T, Crespin M. Large interlayer repeats distances observed for montmorillonites treated by mixed Al-Fe and Fe pillaring solutions[J]. Chemical Communication, 1998, 14(5): 2111-2112.
[12] 从兴顺, 王力, 张明伟. Fe/Cr柱撑蒙脱石的水热法制备与表征[J]. 工 业催化, 2006, 14(5): 61-64. Cong Xingshun, Wang Li, Zhang Mingwei. Preparation of Fe/Crpillared montmorillonite by hydrothermal method and its characterization[J]. Industrial Catalysis, 2006, 14(5): 61-64.
[13] Zhu X X, Wang L, Gao W J. Study on preparation and interlayer ion state of Fe/Ni pillared montmorillonite[J]. Advanced Materials Research, 2014, 873: 267-272.
[14] Salerno P, Mendioroz S, Lopez A. Al-pillared montmorillonite-based NiMo catalysis for HDS and HDN of gas oil: Influence of the method and order of Mo and Ni impregnation[J]. Applied Catalysis A: Genaral, 2004, 259: 17-28
[15] 丛兴顺. 新型Fe/Cr-Si柱撑蒙脱石的制备、表征及应用研究[D]. 青 岛: 山东科技大学化学与环境工程学院, 2006. Cong Xingshun. Studies on preparation, characterization and application of a novel Fe/Cr-Si-Pillared montmorillonite catalyst[D]. Qingdao: College of Chemical and Environmental Engineering, Shandong University of Science and Technology, 2006.
[16] 曹玉红. 微波辐射强化制备改性膨润土及其应用的研究[D]. 南宁: 广西大学, 2004. Cao Yuhong. Study on preparing modified- bentonites by microwave radiation and its application[D]. Nanning: Guangxi University, 2004.
[17] Booij E, Kloprogge J T, van Veen J A R. Preparation, structural characteristecs and catalytic properties of large-pore rare eath element (Ce,La)/Al-pillared smectites[J]. Clays and Clay Minerals, 1996, 44: 774-782.
[18] Pinnavaia T J. Intercalated clay catalysts[J]. Science, 1983, 220 (4595): 365-371.
[19] 达志坚, 闵恩泽. 载铂铝交联蒙脱土的烷烃芳构化特性[J]. 催化学 报, 1994, 15(3): 195-199. Da Zhijian, Min Enze. The aromatization properties of platinum containing cross-linking montmorillonite[J]. Journal of Catalysis, 1994, 15(3): 195-199.
[20] Mao H H, Li B S, Yue L W, et al. Aluminated mesoporous silicapillared montmorillonite as acidic catalyst for catalytic cracking[J]. Applied Clay Science, 2011, 53: 676-683.
[21] Luis A G, Miguel A V, Antonio G. Treatment of municipal leachate of landfill by fenton-like heterogeneous catalytic wet peroxide oxidation using an Al/Fe pillared montmorillonite as active catalyst[J]. Chemical Engineering Journal, 2011, 178: 146-153.
[22] Kanattukara V B, Moon I K, Moon S P, et al. Selective catalytic oxidation of H2S over V2O5-supported Fe-pillared montmorillonite clay[C]. The 6th International Conference on Environmental Catalysis, Beijing, September 12-15, 2010.
[23] Kanattukara V B, Dong K K, Han J C, et al. Synthesis of metal-oxide pillared montmorillonite clay for the selective catalytic oxidation of H2S[J]. Journal of Industrial and Engineering Chemistry, 2010, 16: 593- 597.
[24] Zhang A Q, Zhang R B, Zhang N, et al. Synthesis of new NiO-SiO2- Sol pillared montmorillonite and its catalytic activity in the hydrogenation of benzene[J]. Kinetica and Catalysis, 2010, 51(5): 710-713.
[25] Chen M, Fan L P, Qi L Y, et al. The catalytic combustion of VOCs over copper catalysts supported on cerium-modified and zirconiumpillared montmorillonite[J]. Catalysis Communications, 2009, 10: 838- 841.
[26] Bodman S D, Mcwhinnie W R, Begon V. Metal-ion pillared clays as hydrocracking catalysts(Ⅱ): Effect of contact time on products from coal extracts and petroleum distillation residues[J]. Feul, 2003, 82(18): 2309-2321.
[27] 高剑, 吴棱, 梁诗景, 等. 铁钛双金属共柱撑膨润土光催化-Fenton降 解苯酚[J]. 催化学报, 2010, 31(3): 317-321. Gao Jian, Wu Ling, Liang Shijing, et al. Photocatalysis- Fenton degradation of phenol over Fe-Al pillared bentonite[J]. Journal of Catalysis, 2010, 31(3): 317-321.
[28] Morfis S, Philippopoulos C, Papayannakos N. A application of Al-pillared clay minerals as catalytic carriers for the reaction of NO with CO[J]. Appl Clay Science, 1998, 13(3): 203-212.
[29] Perathoner S, Vaccari A. Catalysts based on pillared interlayered clays for the selective catalytic reduction of NO[J]. Clay Minerals, 1997, 32: 123-134.
[30] 丁雪军, 安太成, 傅家谟, 等. 柱撑粘土复合材料的研究进展及其在 环境污染物治理方面的应用[J]. 地球化学, 2005, 34(6): 626-634. Ding Xuejun, An Taicheng, Fu Jiamo, et al. Study situation of pillared clay and its applications in the environmental pollutants treatment[J]. Geochimica, 2005, 34(6): 626-634.
[31] Wu P X, Zhou J B, Wang X R, et al. Adsorption of Cu- EDTA complexes from aqueous solution by polymeric Fe/Zr pillared montmorillonte: Behaviors and mechanisms[J]. Desalination, 2011, 277: 288-295.
[32] Chen J Y, Liu X L, Li G Y, et al. Synthesis and characterization of novel SiO2 and TiO2 co-pillared montmorillonite composite for adsorption and photocatalytic degradation of hydrophobic organic pollutants in water[J]. Catalysis Today, 2011, 164: 364-369.
[33] Zhou J B, Wu P X, Dang Z, et al. Polymeric Fe/Zr pillared montmorillonite for the removal of Cr(Ⅵ) from aqueous solutions[J]. Chemical Engineering Journal, 2010, 162: 1035-1044.
[34] 吴平霄, 张惠芬, 郭九皋. 无机-有机柱撑蒙脱石对苯酚的吸附[J]. 地 球化学, 1999, 28(1): 58-69. Wu Pingxiao, Zhang Huifen, Guo Jiugao. Adsorption of phenol on inorganic-organic pillared montmorillonite[J]. Geichimica, 1999,28(1): 58-69.
[35] 邵红, 潘波. 铁镍改性膨润土对废水中有机污染物的吸附性能研究[J]. 环境污染治理技术与设备, 2006, 7(6): 92-95. Shao Hong, Pan Bo. Study on Fe-Ni modified montmorillonite removing COD in waster water[J]. Techniques and Equipment for Environmental Pollution Control, 2006, 7(6): 92-95.
[36] Zeng X Q, Liu W P. Adsorption of direct green B on mixed hydrooxy- Fe-Al pillared montmorillonite with large basal spacing[J]. Journal of Environmental Sciences, 2005, 17(1): 159-162.
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