研究论文

油气田现场腐蚀检测装置设计与应用

  • 朱培珂 ,
  • 邓金根 ,
  • 黄凯文 ,
  • 罗宇维 ,
  • 朱江林 ,
  • 吴山
展开
  • 1. 中国石油大学油气资源与探测国家重点实验室, 北京 102249;
    2. 中海石油(中国)有限公司湛江分公司, 湛江 524000;
    3. 中海油田服务股份有限公司, 廊坊 065200
朱培珂,博士研究生,研究方向为油套管的腐蚀与防护,电子信箱:zhupeik@163.com

收稿日期: 2014-01-20

  修回日期: 2014-04-26

  网络出版日期: 2014-07-16

基金资助

米桑油田油套管防腐研究项目

Design and Application of On-line Detecting Device for Corrosion in Oil & Gas Field

  • ZHU Peike ,
  • DENG Jingen ,
  • HUANG Kaiwen ,
  • LUO Yuwei ,
  • ZHU Jianglin ,
  • WU Shan
Expand
  • 1. State Key Laboratory of Petroleum Resource & Prospecting, China University of Petroleum, Beijing 102249, China;
    2. CNOOC (China) Co., Ltd., Zhanjiang Branch, Zhanjiang 524000, China;
    3. China Oilfield Services Limited, Langfang 065200, China

Received date: 2014-01-20

  Revised date: 2014-04-26

  Online published: 2014-07-16

摘要

针对储层流体中高含CO2和H2S 腐蚀性气体的油气田,为了优化防腐选材,使用现场腐蚀检测装置开展实验。指出了现有腐蚀检测装置存在的不足,分析了以辅助评价材质现场腐蚀为目的腐蚀检测装置应具备的结构特点,并设计加工了油气田现场腐蚀检测装置。在设计阶段对现场腐蚀检测装置进行了强度校核,设计了聚四氟乙烯材质的腐蚀挂片悬挂件及与之匹配的梯形横截面腐蚀挂片;在加工完成后进行了试压,确保能够满足现场的最高工作压力。针对该现场腐蚀检测装置提出了具体的应用方法。在米桑油田选择有代表性的生产井,在井口缓释剂投注点之前安装该腐蚀检测装置,进行现场腐蚀实验。设备能够满足现场要求,在规定的时间内完成了预定数量和不同材质的测试,实验结果表明,在含有0.2 MPa CO2储层中,油套管应选用马氏体不锈钢13Cr 不锈钢材质,在含有1.3 MPa CO2及0.8 MPa H2S 的储层中,超级13Cr 不锈钢未发现局部腐蚀且腐蚀速率极低。

本文引用格式

朱培珂 , 邓金根 , 黄凯文 , 罗宇维 , 朱江林 , 吴山 . 油气田现场腐蚀检测装置设计与应用[J]. 科技导报, 2014 , 32(19) : 68 -72 . DOI: 10.3981/j.issn.1000-7857.2014.19.011

Abstract

In optimizing the selection of corrosion-resistant materials and safe and economic casing and tubing materials for oil & gas fields with high content of CO2 and H2S, the oilfield coupon corrosion test plays an important role. The weakness of the current detecting devices of corrosion is shown and the structural features that a detecting device of corrosion should have for the assessment of the steel corrosion under oilfield conditions are analyzed. Based on these analyses, an on-line detecting device of corrosion is designed and manufactured. During the design phase, the strength of the on-line detecting device of corrosion is checked and a PTFE (polytetrafluoroethylene) holder and the coupons with the trapezoidal cross sectional shape are specially designed. After the device is manufactured, the pressure test is carried out to check the device for the maximum working pressure and the specific operation method. The corrosion detecting devices are installed in wells of the Missan oilfield. The device is in the wellhead and before the injection point of the corrosion inhibitor and can meet the requirement of the oilfield. The oilfield test covers the scheduled amount for different materials of coupons during 3 months. The results show that 13Cr martensitic stainless steel can work under the condition of 0.2 MPa CO2 and under the condition of 1.3 MPa CO2, 0.8 MPa H2S, the 13Cr super-martensitic stainless steel shows no local corrosion with a very low corrosion rate.

参考文献

[1] Hideki T, Masakatsu U, Yamamoto E, et al. Research into material selection for down-hole tubing by using dynamic field tester[C]. 10th Abu Dhabi International Petroleum Exhibition and Conference, Abu Dhabi, October 13-16, 2002.
[2] 陈长风, 路民旭, 赵国仙. 温度, Cl-浓度, Cr元素对N80钢CO2腐蚀电 极过程的影响[J]. 金属学报, 2003, 39(8): 848-854. Chen Changfeng, Lu Minxu, Zhao Guoxian. Effects of temperature, Clconcentration and Cr on electrode deactions of CO2 corrosion of N80 steel[J]. Acta Metallurgica Sinica, 2003, 39(8): 848-854.
[3] Kermani B, Martin J W, Esaklul K A. Materials design strategy: Effects of H2S/CO2 corrosion on materials selection[C]. Corrosion, San Diego, California, March 12-16, 2006.
[4] 李建平, 赵国仙, 郝士明. 几种因素对油套管钢CO2腐蚀行为影响[J]. 中国腐蚀与防护学报, 2005, 25(4): 241-244. Li Jianping, Zhao Guoxian, Hao Shiming. Dynamic corrosion behaviors of N80, P105 and SM110 steel[J]. Journal of Chinese Society for Corrosion and Protection, 2005, 25(4): 241-244.
[5] Moosavi A N, Rumash K, Kadri M. Material selection for downhole sour environments[C]. 2008 Abu Dhabi International Petroleum Exhibition and Conference, Abu Dhabi, November 3-6, 2008.
[6] 孙海. 天然气压气站内腐蚀挂片监测管道内腐蚀[J]. 腐蚀与防护, 2011(3): 239-242. Sun Hai. Internal corrosion monitoring of pipelines in natural gas compression stations using corrosion coupons[J]. Corrosion & Protection, 2011(3): 239-242.
[7] 史涛, 梁爱国, 李甫, 等. 油气管道腐蚀挂片悬挂装置的研制与应用[J]. 油气储运, 2012(9): 695-697. Shi Tao, Liang Aiguo, Li Fu, et al. Development and application of corrosion coupon suspension device for oil and gas pipelines[J]. Oil & Gas Storage and Transportation, 2012(9): 695-697.
[8] 中华人民共和国国家质量监督检验检疫总局. GB/T 3098.6-2000 紧 固件机械性能不锈钢螺栓、螺钉和螺柱[S]. 北京: 中国标准出版社, 2001. General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China. GB/T 3098.6-2000 Mechanical properties of fasteners-bolts, screws and studs made of stainless-steel[S]. Beijing: China Standards Press, 2001.
[9] 国家质量技术监督局. GB/T 5783-2000 六角头螺栓全螺纹[S]. 北 京: 中国标准出版社,2000. The State Bureau of Quality and Technical Supervision. GB/T 5783-2000 Hexagon head bolts-full thread[S]. Beijing: China Standards Press, 2000.
[10] 吴宗泽, 罗圣国. 机械设计课程设计手册[M]. 北京: 高等教育出版 社, 2006. Wu Zongze, Luo Shengguo. Curriculum design manual of machinery[M]. Beijing: Higher Education Press, 2006.
[11] 濮良贵, 纪名刚. 机械设计[M]. 北京: 高等教育出版社, 2006. Pu Lianggui, Ji Minggang. Design of machinery[M]. Beijing: Higher Education Press, 2006.
[12] 中华人民共和国国家质量监督检验检疫总局. GB/T 13927-2008 工 业阀门压力试验[S]. 北京: 中国标准出版社, 2009. General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China. GB/T 13927-2008 Industrial valves-pressure testing[S]. Beijing: China Standards Press, 2009.
[13] 万里平, 孟英峰, 李皋, 等. 气体钻井井口腐蚀(冲蚀) 检测装置设计 与应用[J]. 石油机械, 2012, 40(10): 15-17. Wan Liping, Meng Yingfeng, Li Ao, et al. Design and application of the wellhead corrosion (Erosion) detection device for gas drilling[J]. China Petroleum Machinery, 2012, 40(10): 15-17.
[14] The Corrosion Society. NACE RP 0775-2005 preparation, installation, analysis, and interpretation of corrosion coupons in oilfield operations[S]. Houston: NACE International, 2005.
文章导航

/