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2014 , Vol. 32 >Issue 32: 72 - 77

DOI: https://doi.org/10.3981/j.issn.1000-7857.2014.32.012

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锂离子电池层状结构三元正极材料LiNi1/3Co1/3Mn1/3O2研究进展

  • 李继利 ,
  • 曹传宝
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  • 北京理工大学材料学院, 北京 100081
李继利,博士研究生,研究方向为锂离子电池电极材料,电子信箱:lijili328@bit.edu.cn

收稿日期: 2014-06-27

  修回日期: 2014-07-17

  网络出版日期: 2014-11-27

基金资助

国家自然科学基金项目(21371023)

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Research Progress of Layered Structural LiNi1/3Co1/3Mn1/3O2 as a Cathode for Li-ion Battery

  • LI Jili ,
  • CAO Chuanbao
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  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

Received date: 2014-06-27

  Revised date: 2014-07-17

  Online published: 2014-11-27

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摘要

三元层状结构LiNi1/3Co1/3Mn1/3O2具有较高的可逆容量、结构稳定性、热稳定性和相对较低的成本,成为电动汽车领域最具前景的锂离子电池正极材料之一。综述了锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2的结构、电化学性能及对其进行性能优化的掺杂、表面包覆和制备特殊纳米结构材料的3 种方法。其中,纳米材料的研究是锂离子电池正极材料的研究热点之一。材料的电化学性能与粒子尺寸、形貌、多孔性、结晶性和比表面积紧密相关。因此,提高正极材料LiNi1/3Co1/3Mn1/3O2的电化学性能时,要充分考虑到这些因素的影响。

关键词： 锂离子电池; 正极材料; 层状结构; LiNi1/3Co1/3Mn1/3O2

本文引用格式

李继利 , 曹传宝 . 锂离子电池层状结构三元正极材料LiNi1/3Co1/3Mn1/3O2研究进展[J]. 科技导报, 2014 , 32(32) : 72 -77 . DOI: 10.3981/j.issn.1000-7857.2014.32.012

Abstract

Layered structural LiNi1/3Co1/3Mn1/3O2 is one of the most promising materials used as a cathode for Li-ion battery in electric vehicles, mainly due to the high capacity, the stable structure, the thermal stability and the low cost of LiNi1/3Co1/3Mn1/3O2. In this review, the structure, the electrochemical performances and the methods for improving its electrochemical performances of LiNi1/3Co1/3Mn1/3O2, such as doping with other ions, coating with other materials and the preparation of special structural nanomaterials, are included. In recent years, the researchers on Li-ion battery are concerned with various nanomaterials. The electrochemical performances of materials are closely related with the size, the morphology, the porosity, the crystalline features and the specific surface area of the material. Therefore, these effects should be considered for improving the electrochemical performances of LiNi1/3Co1/3Mn1/3O2 cathodes.

Key words： lithium ion battery; cathode; layered structure; LiNi1/3Co1/3Mn1/3O2

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