专题论文

秦俑博物馆室内气溶胶的演化特征及影响因素

  • 李华 ,
  • 胡塔峰 ,
  • 曹军骥 ,
  • 贾文婷 ,
  • 马涛 ,
  • 王春燕
展开
  • 1. 秦始皇帝陵博物院, 陶质彩绘文物保护国家文物局重点科研基地, 西安710600;
    2. 中国科学院大学, 北京100049;
    3. 中国科学院地球环境研究所气溶胶化学与物理重点实验室, 西安710061;
    4. 西安交通大学全球环境变化研究院, 西安710049;
    5. 陕西省文物保护研究院, 西安710075
李华,博士研究生,研究方向为大气环境科学,电子信箱llhh669@sohu.com

收稿日期: 2015-01-23

  修回日期: 2015-02-15

  网络出版日期: 2015-04-10

基金资助

国家科技支撑计划项目(2012BAK14B01);国家自然科学基金项目(41271480);国家文物局课题(20120219)

Evolution of indoor aerosol in Emperor Qin's Terra-cotta Museum and its influential factors

  • LI Hua ,
  • HU Tafeng ,
  • CAO Junji ,
  • JIA Wenting ,
  • MA Tao ,
  • WANG Chunyan
Expand
  • 1. Key Scientific Research Base of Ancient Polychrome Pottery Conservation, SACH; Emperor Qin Shihuang's Mausoleum Site Museum, Xi'an 710600, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China;
    3. Key Lab of Aerosol Chemistry & Physics, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China;
    4. Institute of Global Environmental Change, Xi'an Jiaotong University, Xi'an 710049, China;
    5. Shaanxi Institute for the Preservation of Cultural Heritage, Xi'an 710075, China

Received date: 2015-01-23

  Revised date: 2015-02-15

  Online published: 2015-04-10

摘要

分析了2013 年秦俑博物馆(秦俑馆)1 号坑遗址保护展示厅的室内空气质量, 包括微气候条件、气溶胶质量浓度及化学组成的冬、夏季特征, 并通过探讨其在1989 至2013 年间的演化, 评价博物馆的旅游规划和环境改善政策对文物保存大气环境的长期影响。自20 世纪90 年代开始, 秦俑馆内一系列环境措施的实施和旅游条件的建设, 对秦俑馆室内的气溶胶及其组成产生了显著的影响。其中, 夏季室内总悬浮颗粒物(TSP)的质量浓度由1994 年的540.0 μg·m-3降低至2004 年的172.4 μg·m-3, 冬季TSP 的质量浓度由1994 年的380.0 μg·m-3降低至2005 年的312.5 μg·m-3。夏季PM2.5的质量浓度由2004 的108.4 μg·m-3降低至2013 的65.7 μg·m-3, 冬季PM2.5的质量浓度由2005 的242.3 μg·m-3降低至2013 的98.6 μg·m-3。尽管如此, 秦俑馆内的文物依然面临气溶胶酸性组分的长期威胁。

本文引用格式

李华 , 胡塔峰 , 曹军骥 , 贾文婷 , 马涛 , 王春燕 . 秦俑博物馆室内气溶胶的演化特征及影响因素[J]. 科技导报, 2015 , 33(6) : 46 -53 . DOI: 10.3981/j.issn.1000-7857.2015.06.007

Abstract

Long-term measurement results of indoor air quality (IAQ) from 1989 to 2013 inside Pit No.1, the largest display hall in Emperor Qin's Terra-cotta Museum (QTM) were used to evaluate the effectiveness of measures for conservation environment improvement of antiques. By comparing the results of sampling campaigns in 2013 with databases in 1989, 2004-2005, 2006-2007, and 2011, seasonal and inter-annual variations in microclimate and aerosol chemical compositions were incorporated in estimating the probable influences of management of surroundings, tourist flow, excavation and restoration task, and renovation and/or new construction work on IAQ in the QTM. Since the implementation of the environmental policies of 1990s, a significant decrease of indoor particulate matter mass for the QTM has been achieved. The mass concentrations of summer TSP decreased from 540.0 μg·m-3 in 1994 to 172.4 μg·m-3 in 2004, as well as the winter TSP decreased from 380.0 μg·m-3 in 1994 to 312.5 μg·m-3 in 2005. The mass concentration of summer PM2.5 decreased from 108.4 μg·m-3 in 2004 to 65.7 μg·m-3 in 2013, as well as the winter PM2.5 from 242.3 μg·m-3 in 2005 to 98.6 μg·m-3 in 2013. However, it is noted that potential hazards due to the secondary particulate acidic species in indoor air should still be considered to ensure the long-term preservation and conservation of the museum's artifact collection.

参考文献

[1] Thomson G. Air pollution-A review for conservation chemists[J]. Studies in Conservation, 1965, 10(4): 147-167.
[2] Baer N S, Banks P N. Indoor air pollution: Effects on cultural and historical materials[J]. International Journal of Museum Manage Curatorship, 1985, 4(1): 9-20.
[3] Brimblecombe P. The composition of museum atmospheres[J]. Atmospheric Environment, 1990, 24(1): 1-8.
[4] Nazaroff W W, Salmon L G, Cass G R. Concentration and fate of airborne particles in museums[J]. Environmental Science & Technology, 1990, 24 (1): 66-77.
[5] Brimblecombe P, Blades N, Camuffo D, et al. The indoor environment of a modern museum building, the sainsbury centre for Visual Arts, Norwich, UK[J]. Indoor Air, 1999, 9(3): 146-164.
[6] De Bock L A, van Grieken R E, Camuffo D, et al. Microanalysis of museum aerosols to elucidate the soiling of paintings: Case of the Correr Museum, Venice, Italy[J]. Environmental Science & Technology, 1996, 30(11): 3341-3350.
[7] Broughton L. Report of commission on the site for a new National Gallery[J]. British Sessional Papers, House of Commons, Session, 1857, 2: 24.
[8] Ligocki M P, Liu H I H, Cass G R, et al. Measurements of particle deposition rates inside southern California museums[J]. Aerosol Science and Technology, 1990, 13(1): 85-101.
[9] Grosjean D, Salmon L G, Cass G R. Fading of organic artists' colorants by atmospheric nitric acid: Reaction products and mechanisms[J].Environmental Science & Technology, 1992, 26(5): 952-959.
[10] Gysels K, Deutsch F, van Grieken R. Characterisation of particulate matter in the Royal Museum of fine arts, Antwerp, Belgium[J]. Atmospheric Environment, 2002, 36(25): 4103-4113.
[11] Camuffo D, Brimblecombe P, van Grieken R, et al. Indoor air quality at the Correr Museum, Venice, Italy[J]. Science of the Total Environment, 1999, 236(1): 135-152.
[12] Worobiec A, Samek L, Karaszkiewicz P, et al. A seasonal study of atmospheric conditions influenced by the intensive tourist flow in the Royal Museum of Wawel Castle in Cracow, Poland[J]. Microchemical Journal, 2008, 90(2): 99-106.
[13] 曹军骥. 我国PM2.5污染现状与控制对策[J]. 地球环境学报, 2012, 3: 1030-1036. Cao Junji. Pollution status and control strategies of PM2.5 in China[J]. Journal of Earth Environment, 2012, 3: 1030-1036.
[14] Christoforou C S, Salmon L G, Cass G R. Fate of atmospheric particles within the Buddhist cave temples at Yungang, China[J]. Environmental Science & Technology, 1996, 30(12): 3425-3434.
[15] Christoforou C S, Salmon L G, Cass G R. Passive filtration of airborne particles from buildings ventilated by natural convection: Design procedures and a case study at the Buddhist cave temples at Yungang, China[J]. Aerosol Science & Technology, 1999, 30(6): 530-544.
[16] Cao J, Rong B, Lee S, et al. Composition of indoor aerosols at Emperor Qin's Terra-cotta Museum, Xi'an, China, during summer, 2004[J]. China Particuology, 2005, 3(3): 170-175.
[17] Cao J, Li H, Chow J C, et al. Chemical composition of indoor and outdoor atmospheric particles at Emperor Qin's Terra-cotta Museum, Xi'an, China[J]. Aerosol and Air Quality Resarch, 2011, 11(1): 70-79.
[18] Hu T, Lee S, Cao J, et al. Characterization of winter airborne particles at Emperor Qin's Terra-cotta Museum, China[J]. Science of the Total Environment, 2009, 407(20): 5319-5327.
[19] Hu T, Cao J, Ho K, et al. Winter and summer characteristics of airborne particles inside Emperor Qin's Terra-Cotta Museum, China: A study by scanning electron microscopy-energy dispersive X-Ray spectrometry[J]. Journal of the Air & Waste Management Association, 2011, 61(9): 914-922.
[20] Huang R J, Zhang Y, Bozzetti C, et al. High secondary aerosol contribution to particulate pollution during haze events in China[J]. Nature, 2014, 514(7521): 218-222.
[21] 曹军骥. PM2.5与环境[M]. 北京: 科学出版社, 2014. Cao Junji. PM2.5 and environment[M]. Beijing: Science Press, 2014.
[22] 秦始皇兵马俑博物馆年鉴[M]. 1990—2013. Yearbook of Emperor Qin's Terra-cotta Museum[M]. 1990—2013.
[23] 张志军. 秦始皇兵马俑保护研究[M]. 西安: 陕西人民教育出版社, 1998. Zhang Zhijun. Study on environmental quality of Emperor Qin's Terracotta Museum[M]. Xi'an: Shaanxi People's Education Press, 1998.
[24] 董俊刚. 兵马俑博物馆室内气溶胶理化特征与来源解析[D]. 西安: 中国科学院地球环境研究所, 2008. Dong Jungang. The physical and chemical characteristics and source appointment of indoor aerosols at Emperor Qin's Terra-cotta Museum, Xi'an, China[D]. Xi'an: Institute of Earth Environment, CAS, 2008.
[25] 李华, 王文佳, 赵凤艳, 等. 被动采样—离子色谱法对秦俑遗址环境 腐蚀性气体的检测研究[J]. 文物保护与考古科学, 2014, 26(4): 54-61. Li Hua, Wang Wenjia, Zhao Fengyan, et al. Passive sampling and ion chromatography measurement of corrosive gases in Emperor Qin's Terracotta Warriors and Horses Museum[J]. Sciences of Conservation and Archaeology, 2014, 26(4): 54-61.
[26] Xu H M, Cao J J, Ho K F, et al. Lead concentrations in fine particulate matter after the phasing out of leaded gasoline in Xi'an, China[J]. Atmospheric Environment, 2012, 46: 217-224.
[27] Chow J C, Watson J G. Ion chromatography in elemental analysis of airborne particles[J]. Elemental Analysis of Airborne Particles, 1999, 1: 97-137.
[28] Cao J J, Lee S C, Ho K F, et al. Characteristics of carbonaceous aerosol in Pearl River Delta Region, China during 2001 winter period[J]. Atmospheric Environment, 2003, 37(11): 1451-1460.
[29] Kerminen V M, Hillamo R, Teinil? K, et al. Ion balances of sizeresolved tropospheric aerosol samples: Implications for the acidity and atmospheric processing of aerosols[J]. Atmospheric Environment, 2001, 35(31): 5255-5265.
[30] Pierson W R, Brachaczek W W, McKee D E. Sulfate emissions from catalyst-equipped automobiles on the highway[J]. Journal of the Air Pollution Control Association, 1979, 29(3): 255-257.
[31] Truex T J, Pierson W R, McKee D E. Sulfate in diesel exhaust[J]. Environmental Science & Technology, 1980, 14(9): 1118-1121.
[32] Ohta S, Okita T. A chemical characterization of atmospheric aerosol in Sapporo[J]. Atmospheric Environment. Part A. General Topics, 1990, 24 (4): 815-822.
[33] Cao J J, Zhang T, Chow J C, et al. Characterization of atmospheric ammonia over Xi'an, China[J]. Aerosol and Air Quality Resarch, 2009, 9 (2): 277-289.
[34] 金丽娜, 王建鹏, 张弘. 近40 a来西安市区与郊县气温变化特征对比[J]. 干旱气象, 2013, 31(4): 720-725. Jin Lina, Wang Jianpeng, Zhang Hong. Comparative analysis on temperature changes in city and suburbs of Xi'an over the past 40 years[J]. Journal of Arid Meteorology, 2013, 31(4), 720-725.
文章导航

/