综述文章

新型空气净化器及其评价方法

  • 路丽 ,
  • 贺军辉 ,
  • 田华 ,
  • 何溥 ,
  • 杨巧文
展开
  • 1. 中国矿业大学(北京)化学与环境工程学院, 北京100083;
    2. 中国科学院理化技术研究所, 北京100190
路丽, 硕士研究生, 研究方向为环境催化材料的合成及其应用, 电子信箱:llsyf114@163.com

收稿日期: 2015-03-04

  修回日期: 2015-04-23

  网络出版日期: 2015-07-15

基金资助

国家自然科学基金项目(21271177, 21007076)

Novel air cleaners and their evaluation methods

  • LU Li ,
  • HE Junhui ,
  • TIAN Hua ,
  • HE Pu ,
  • YANG Qiaowen
Expand
  • 1. School of Chemistry and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China;
    2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Received date: 2015-03-04

  Revised date: 2015-04-23

  Online published: 2015-07-15

摘要

随着雾霾天气日益频繁, 室内空气质量备受关注, 传统的室内空气净化器已不能满足室内空气净化的要求, 研发新型多功能空气净化器及复合空气净化技术已成为净化器发展的主要方向。本文总结近年来国内外对室内空气净化器的相关研究, 综述当前应用最广泛的几种新型室内空气净化器(包括新型吸附材料、低温等离子体、光催化、催化氧化、复合式空气净化器)的研发进展, 分析各净化器的优势与不足, 总结新型空气净化器的主要评价指标及评价方法, 分析其气体污染物、固体颗粒物、微生物污染物进行单一评价的方法, 并展望室内空气净化器的研发方向。

本文引用格式

路丽 , 贺军辉 , 田华 , 何溥 , 杨巧文 . 新型空气净化器及其评价方法[J]. 科技导报, 2015 , 33(12) : 101 -109 . DOI: 10.3981/j.issn.1000-7857.2015.12.017

Abstract

More and more frequent haze days increase the concern over indoor air quality. Traditional indoor air cleaners no longer satisfy the requirements of indoor air purification. Thus, development of novel multifunctional air cleaners and comprehensive air purification technologies become a major research direction toward improving indoor air quality and meeting new needs of current market. By summarizing recent researches on indoor air cleaners of both at home and abroad, herein we review several novel indoor air cleaners, including new adsorption materials, non- thermal plasma, photocatalytic, catalytic oxidation and multifunctional air cleaners, and analyze their advantages and disadvantages. The main evaluation indexes and methods of novel air cleaners are also summarized, including the evaluation methods for gas pollutants, solid particles and microbial contaminants. An outlook is also made toward the future research directions of indoor air cleaners.

参考文献

[1] Branco P T B S, Alvim-Ferraz M C M A, Martins F G, et al. Indoor air quality in urban nurseries at Porto city: Particulate matter assessment [J]. Atmospheric Environment, 2014, 84: 133-143.
[2] Bjarke M, Antti J K, Tareq H, et al. A new clean air delivery rate test applied to five portable indoor air cleaners[J]. Aerosol Science and Technology, 2014, 48(4): 409-417.
[3] Zhang Y, Mo J, Li Y, et al. Can commonly-used fan-driven air cleaning technologies improve indoor air quality? A literature review[J]. Atmospheric Environment, 2011, 45: 4329-4343.
[4] 励建荣, 王立娜, 金毅, 等. 国内外空气净化消毒技术的研究进展[J]. 环境科学与技术, 2014, 37(6N): 204-209. Li Jianrong, Wang Lina, Jin Yi, et al. The research progress on air purification disinfection technology at home and abroad[J]. Environmental Science & Technology, 2014, 37(6N): 204-209.
[5] Dela Cruz M, Christensen J H, Thomsen J D, et al. Can ornamental potted plants remove volatile organic compounds from indoor air-a review[J]. Environmental Science and Pollution Research International, 2014, 21 (24): 13909-13928.
[6] 陈晓淼, 刘峥军, 郑浩, 等. 室内空气净化方法及研究进展[J]. 轻工科 技, 2014, 185(4): 62-63. Chen Xiaomiao, Liu Zhengjun, Zheng Hao, et al. The research progress of indoor air purification methods[J]. Light Industry Science and Technology, 2014, 185(4): 62-63.
[7] Hao J, Zhu T, Fan X. Indoor air pollution and its control in China[M]// The Handbook of Environmental Chemistry. Berlin Heidelberg: Springer, 2014.
[8] Yu B F, Hu Z B, Liu M, et al. Review of research on air-conditioning systems and indoor air quality control for human health[J]. International Journal of Refrigeration, 2009, 32: 3-20.
[9] 王佳媛. 室内空气净化材料与技术应用研究进展[J]. 科学咨询(科技· 管理), 2012(7): 58-59. Wang Jiayuan. The research progress on indoor air purification materials and technology application[J]. Technology & Management, 2012(7): 58-59.
[10] 李俊宁, 王丽娜, 齐涛, 等. 介孔气体吸附剂[J]. 化学进展, 2008, 20 (6): 851-858. Li Junning, Wang Lina, Qi Tao, et al. Mesoporous gas adsorbents[J]. Progress in Chemistry, 2008, 20(6): 851-858.
[11] Jo W K, Chun H H. Application of fibrous activated carbon filter in continuous-flow unit for removal of volatile organic compounds under simulated indoor conditions[J]. Aerosol and Air Quality Research, 2014, 14: 347-354.
[12] Shen J H, Wang Y S, Lin J P, et al. Improving the indoor air quality of respiratory type of medical facility by zeolite filtering[J]. Journal of the Air & Waste Management Association, 2014, 64(1): 13-18.
[13] Ding Z, Xie Y, Yan K, et al. Non-thermal plasma technique and its application in the field of environmental protection[J]. Advances in Environmental Protection, 2014, 4: 136-145.
[14] 郑超, 徐羽贞, 黄逸凡, 等. 低温等离子体灭菌及生物医药技术研究 进展[J]. 化工进展, 2013, 32(9): 2185-2193. Zheng Chao, Xu Yuzhen, Huang Yifan, et al. State-of-the-art nonthermal plasma disinfection and medicine[J]. Chemical Industry and Engineering Progress, 2013, 32(9): 2185-2193.
[15] Schmid S, Jecklin M C, Zenobi R. Degradation of volatile organic compounds in a non- thermal plasma air purifier[J]. Chemosphere, 2010, 79(2): 124-130.
[16] Oda T. Non-thermal plasma processing for environmental protection: Decomposition of dilute VOCs in air[J]. Journal of Electrostatics, 2003, 57: 293 -311.
[17] 伶伟钢, 王维宽, 胡贇. 室内空气净化技术及其发展趋势[J]. 科技创 新导报, 2013, 17: 125-126. Ling Weigang, Wang Weikuan, Hu Yun. Technology and development of indoor air purification[J]. Science and Technology Innovation Herald, 2013, 17: 125-126.
[18] Zhao D Z, Li X S, Shi C, et al. Low- concentration formaldehyde removal from air using a cycled storage – discharge (CSD) plasma catalytic process[J]. Chemical Engineering Science, 2011, 66(17): 3922-3929.
[19] Ayoko G A, Wang H. Volatile organic compounds in indoor environments [M]//The Handbook of Environmental Chemistry. Berlin Heidelberg: Springer, 2014.
[20] Pei C C, Leung W W F. Solar photocatalytic oxidation of NO by electronspun TiO2/ZnO composite nanofiber mat for enhancing indoor air quality[J]. Journal of Chemical Technology & Biotechnology, 2014, 89(11): 1646-1652.
[21] Farhanian D, Haghighat F. Photocatalytic oxidation air cleaner: Identification and uantification of by- products[J]. Building and Environment, 2014, 72: 34-43.
[22] 石芳芳, 邱利民, 于川, 等. 室内空气净化技术及产品综述[J]. 制冷 学报, 2014, 35(5): 14-18. Shi Fangfang, Qiu Limin, Yu Chuan, et al. Techniques and products for air purification[J]. Journal of refrigeration, 2014, 35(5): 14-18.
[23] Lü J, Zhu L. Highly efficient indoor air purification using adsorptionenhanced- photocatalysis- based microporous TiO2 at short residence time[J]. Environmental Technology, 2013, 34(11): 1447-1454.
[24] 何运兵, 纪红兵, 王乐夫. 室内甲醛催化氧化脱除的研究进展[J]. 化 工进展, 2007, 26(8): 1104-1109. He Yunbing, Ji Hongbing, Wang Lefu. Development of the removal of indoor formaldehyde with catalytic oxidation[J]. Chemical Industry and Engineering Progress, 2007, 26(8): 1104-1109.
[25] Lin L, Chai Y, Zhao B, et al. Photocatalytic oxidation for degradation of VOCs[J]. Open Journal of Inorganic Chemistry, 2013, 3(1): 14-25.
[26] Han Z N, Chang W C, Wang X P, et al. Experimental study on visible-light induced photocatalytic oxidation of gaseous formaldehyde by polyester fiber supported photocatalysts[J]. Chemical Engineering Journal, 2013, 218: 9-18.
[27] Carrillo A M, Carriazo J G. Cu and Co oxides supported on halloysite for the total oxidation of toluene[J]. Applied Catalysis B: Environmental, 2015, 164: 443-452.
[28] Wahid S, Tatarchuk B J. Catalytic material with enhanced contacting efficiency for volatile organic compound removal at ultrashort contact time[J]. Industrial & Engineering Chemistry Research, 2013, 52(44): 15494-15503.
[29] Lestinsky P, Brummer V, Jecha D, et al. Design of an catalytic oxidation unit for elimination of volatile organic compound and carbon monoxide[J]. Industrial & Engineering Chemistry Research, 2014, 53 (2): 732-737.
[30] Chen C, Wu Q, Chen F, et al. Aluminium-rich Beta zeolite-supported platinum nanoparticles for the low- temperature catalytic removal of toluene[J]. Journal of Materials Chemistry A, 2015(3): 5556-5562.
[31] Zhang C, Liu F, Zhai Y, et al. Alkali-metal-promoted Pt/TiO2 opens a more efficient pathway to formaldehyde oxidation at ambient temperatures[J]. Angewandte Chemie, 2012, 51(38): 9628-9632.
[32] 杨全, 张浩, 卜龙利. 复合载体负载型催化剂制备及其微波辅助催化 氧化甲苯性能试验[J]. 西安建筑科技大学学报: 自然科学版, 2014, 46(1): 131-136. Yang Quan, Zhang Hao, Bu Longli. The preparation of composite supported catalyst and the toluene performance test with microwave assisted catalytic oxidation[J]. Journal of Xi'an University of Architecture & Technology: Natural Science Edition, 2014, 46(1): 131-136.
[33] 张长斌, 贺泓, 王莲, 等. 负载型贵金属催化剂用于室温催化氧化甲 醛和室内空气净化[J]. 科学通报, 2009, 54(3): 278-286. Zhang Changbin, He Hong, Wang Lian, et al. Supported noble metal catalysts for the removal of formaldehyde and indoor air purification with catalytic oxidation at room temperature[J]. Chinese Science Bulletin, 2009, 54(3): 278-286.
[34] Yu X, He J, Wang D, et al. Au-Pt bimetallic nanoparticles supported on nest-like MnO2: Synthesis and application in HCHO decomposition [J]. Journal of Nanoparticle Research, 2012, 14(11): 1260.
[35] Wang L, Sakurai M, Kameyama H. Study of catalytic decomposition of formaldehyde on Pt/TiO2 alumite catalyst at ambient temperature[J]. Journal of hazardous materials, 2009, 167(1-3): 399-405.
[36] Huang H, Ye D. Combination of photocatalysis downstream the nonthermal plasma reactor for oxidation of gas-phase toluene[J]. Journal of Hazardous Materials, 2009, 171(1-3): 535-541.
[37] 林民政. 室内空气污染治理研究进展[J]. 海峡科学, 2014, 91(7): 46- 48. Lin Minzheng. The research progress on Indoor air pollution control [J]. Straits Science, 2014, 91(7): 46-48.
[38] Sivachandiran L, Thevenet F, Gravejat P, et al. Isopropanol saturated TiO2 surface regeneration by non- thermal plasma: Influence of air relative humidity[J]. Chemical Engineering Journal, 2013, 214: 17-26.
[39] Maciuca A, Batiot-Dupeyrat C, Tatibouët J M. Synergetic effect by coupling photocatalysis with plasma for low VOCs concentration removal from air[J]. Applied Catalysis B: Environmental, 2012, 125: 432-438.
[40] Ochiai T, Hayashi Y, Ito M, et al. An effective method for a separation of smoking area by using novel photocatalysis- plasma synergistic aircleaner[ J]. Chemical Engineering Journal, 2012, 209: 313-317.
[41] Raso R A, Stoessel P R, Stark W J. Physical mixtures of CeO2 and zeolites as regenerable indoor air purifiers: Adsorption and temperature dependent oxidation of VOC[J]. Journal of Materials Chemistry A, 2014(2): 14089-14098.
[42] Sekine Y, Fukuda M, Takao Y, et al. Simultaneous removal of formaldehyde and benzene in indoor air with a combination of sorption- and decomposition- type air filters[J]. Environmental Technology, 2011, 32(16): 1983-1989.
[43] 孙丽, 王维宽, 胡贇. 室内空气净化关键技术研究[J]. 环境保护与循 环经济, 2013(11): 44-46. Sun Li, Wang Weikuan, Hu Yun. The key techniques of indoor air purification[J]. Environmental Protection and Circular Economy, 2013 (11): 44-46.
[44] 胡晓微, 张于峰, 谢朝国, 等. 室内空气净化器性能评价指标的试验 研究[J]. 安全与环境学报, 2012, 12(5): 64-68. Hu Xiaowei, Zhang Yufeng, Xie Chaoguo, et al. Experimental study of the evaluating indicators for the room- conditioning air cleaners[J]. Journal of Safety and Environment, 2012, 12(5): 64-68.
[45] 中国家用电器研究所, 中国预防医学科学院环境卫生监测所, 北京 华夏环境工程公司, 等. GB/T 18801—2002空气净化器[S]. 北京: 中 国标准出版社, 2002. China's Household Electrical Appliances Research Institute, Environmental Health Monitoring by Chinese Academy of Preventive Medicine, Beijing Huaxia Environmental Engineering Company, et al. GB/T 18801-2002 air cleaner[S]. Beijing: China Standard Press, 2002.
[46] 张妍, 李振海. 室内空气净化器性能指标的探讨[J]. 环境与健康杂 志, 2007, 24(6): 453-455. Zhang Yan, Li Zhenhai. Study of the performance indicators for the indoor air cleaners[J]. Journal of Environment and Health, 2007, 24 (6): 453-455.
[47] 王超, 赵彬, 杨旭东. 一种评价挥发性有机物污染水平的室内空气质 量健康指数[J]. 中南大学学报: 自然科学版, 2014, 45(6): 2099-2104. Wang Chao, Zhao Bin, Yang Xudong. Indoor air quality health index based on evaluation of volatile organic compounds pollution[J]. Journal of Central South University: Science and Technology Edition 2014, 45(6): 2099-2104.
[48] 中国家用电器研究院, 北京亚都科技股份有限公司, 国家家用电器 质量监督检验中心,等. GB/T 18801—2008空气净化器[S]. 北京: 中 国标准出版社, 2008. China's Household Electrical Appliances Research Institute, Beijing Yadu Technology Co., Ltd., National Quality Supervision and Inspection Center Home Appliances, et al. GB/T 18801- 2008 air Cleaner[S]. Beijing: China Standard Press, 2008.
[49] Howard-Reed C, Nabinger S J, Emmerich S J. Characterizing gaseous air cleaner performance in the field[J]. Building and Environment, 2008, 43: 368-377.
[50] Howard-Reed C, Henzel V, Nabinger S J, et al. Development of afield testmethod to evaluate gaseous air cleaner performance in a multizone building[J]. Journal of the Air and Waste Management Association, 2008, 58(7): 919-927.
[51] Yu K P, Lee G W M, Hsieh C P, et al. Evaluation of ozone generation and indoor organic compounds removal by air cleaners based on chamber tests[J]. Atmospheric Environment, 2011, 45(1): 35-42.
[52] Kim H J, Han B, Kim Y J, et al. Efficient test method for evaluating gas removal performance of room air cleaners using FTIR measurement and CADR calculation[J]. Building and Environment, 2012, 47: 385-393.
[53] Gallego E, Roca F J, Perales J F, et al. Experimental evaluation of VOC removal efficiency of a coconut shell activated carbon filter for indoor air quality enhancement[J]. Building and Environment, 2013, 67: 14-25.
[54] 黄芳, 朱志鑫, 吴惠勤, 等. 空气净化产品降解空气污染物效能的测 定方法[J]. 理化检验(化学分册), 2014, 50(3): 288-293. Huang Fang, Zhu Zhixin, Wu Huiqin, et al. Method for determination of efficiency of degradation of air pollutants by air purifiers[J]. Physical Testing and Chemical Analysis (Part B: Chemical Analysis), 2014, 50(3): 288-293.
[55] 李睦, 卜钟鸣, 莫金汉, 等. 我国空气净化器标准存在的问题及相关 思考[J]. 暖通空调, 2013, 43(12): 59-63. Li Mu, Bu Zhongming, Mo Jinhan, et al. Problems and thoughts about Chinese standards for air cleaners[J]. Heating Ventilating & Air Conditioning, 2013, 43(12): 59-63.
[56] Grinshpun S A, Mainelis G, Trunov M, et al. Evaluation of ionic air purifiers for reducing aerosol exposure in confined indoor spaces[J]. Indoor Air, 2005, 15(4): 235-245.
[57] Sultan Z M, Nilsson G J, Magee R J. Removal of ultrafine particles in indoor air: Performance of various portable air cleaner technologies [J]. HVAC&R Research, 2011, 17(4): 513-525.
[58] 李睦, 张晓, 朱焰, 等. 空气净化器去除颗粒物的洁净空气量衰减评 价方法[J]. 绿色建筑, 2014(1): 21-23. Li Mu, Zhang Xiao, Zhu Yan, et al. Clean air attenuation evaluation method on PM eliminating capability of air cleaner[J]. Green Building, 2014(1): 21-23.
[59] 清华大学, 上海市建筑科学研究院(集团)有限公司, 远大空调有限公 司, 等. JG/T 294—2010空气净化器污染物净化性能测定[S]. 北京: 中国标准出版社, 2010. Tsinghua University, Shanghai Building Scientific Research Institute (Group) Co., Ltd., Broad Air Conditioner Co., Ltd, et al. JG/T 294- 2010 test of pollutant cleaning performance of air cleaner[S]. Beijing: China Standard Press, 2010.
文章导航

/