研究论文

添加纳米Al微粒对纯钛微弧氧化膜层性能的影响

  • 周琳燕 ,
  • 古雅菁 ,
  • 欧阳小琴 ,
  • 肖胜辉 ,
  • 张斌斌 ,
  • 万莹 ,
  • 王春霞 ,
  • 冯长杰
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  • 1. 中航工业江西洪都航空工业股份有限公司理化测试中心, 南昌330024;
    2. 中航工业江西洪都航空工业股份有限公司科技部, 南昌330024;
    3. 南昌航空大学材料学院, 南昌330063
周琳燕,高级工程师,研究方向为材料表面技术与分析,电子信箱:zly770517@sina.com;冯长杰,教授,研究方向为材料表面技术与改性,电子信箱:chjfengniat@126.com

收稿日期: 2015-04-20

  修回日期: 2015-06-25

  网络出版日期: 2015-08-28

基金资助

江西省自然科学基金项目(20151BAB206010)

Effects of adding nano-Al particles into electrolyte on the performance of micro-arc oxidation coating formed on pure titanium

  • ZHOU Linyan ,
  • GU Yajing ,
  • OUYANG Xiaoqin ,
  • XIAO Shenghui ,
  • ZHANG Binbin ,
  • WAN Ying ,
  • WANG Chunxia ,
  • FENG Changjie
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  • 1. Physical & Chemical Test Center, AVIC Jiangxi Hongdu Aviation Industry Group Co., Ltd., Nanchang 330024, China;
    2. Department of Science and Technology, AVIC Jiangxi Hongdu Aviation Industry Group Co., Ltd., Nanchang 330024, China;
    3. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

Received date: 2015-04-20

  Revised date: 2015-06-25

  Online published: 2015-08-28

摘要

在微弧氧化电解液中添加纳米Al 微粒,在纯钛表面进行微弧氧化制备Al2O3/TiO2复合微弧氧化膜,采用Quant 200 型扫描电子显微镜(SEM)观察膜层的表面形貌,并研究纳米Al 微粒对微弧氧化复合膜层硬度和耐磨性能的影响。结果表明,纳米Al微粒的添加可使纯钛微弧氧化膜的表面更加平整致密,硬度和耐磨性显著提高。电解液中添加3 g/L 纳米Al 微粒后,微弧氧化的终止电压由460 V 上升至515 V,硬度由811 HV 提高至1232 HV,平均摩擦系数由0.68 降低至0.57,磨损失重由1.0 mg 降低至0.58 mg。

本文引用格式

周琳燕 , 古雅菁 , 欧阳小琴 , 肖胜辉 , 张斌斌 , 万莹 , 王春霞 , 冯长杰 . 添加纳米Al微粒对纯钛微弧氧化膜层性能的影响[J]. 科技导报, 2015 , 33(15) : 50 -53 . DOI: 10.3981/j.issn.1000-7857.2015.15.007

Abstract

The micro-arc oxidation technology is employed to prepare an Al2O3/TiO2 composite coating on pure titanium with Al particles addition into electrolyte. The surface morphology of micro-arc oxidation composite coating is investigated by Quant 200 SEM. The properties of Al2O3/TiO2 composite coating are investigated in terms of the hardness and abrasion resistance of micro-arc oxidation with different Al particle concentrations. The results show that micro-arc oxidation technology can be introduced to prepare Al2O3/TiO2 composite coating. The addition of Al particle into the electrolyte can improve the compactness, abrasion resistance and hardness of micro-arc oxidation composite coating. The termination voltage of micro oxidation increases from 460 V to 515 V, the hardness increases from 811 HV to 1232 HV, the average friction coefficient decreases from 0.68 to 0.57, and the wear weightlessness reduces from 1.0 mg to 0.58 mg when the content of Al particles is 3 g/L.

参考文献

[1] 贾新云, 刘培英, 陶冶, 等. 钛合金的高温氧化及防护[J]. 航空工程与 维修, 2000(4): 19-21. Jia Xinyun, Liu Peiying, Tao Ye, et al. The high temperature oxidation and protection of titanium alloy[J]. Aviation Engineering and maintenance, 2000(4): 19-21.
[2] 陈妍君, 冯长杰, 邵志松, 等. 铝合金微弧氧化技术的研究进展[J]. 材 料导报, 2010, 24(5): 132-137. Chen Yanjun, Feng Changjie, Shao Zhisong, et al. Research progress of micro-arc oxidation on aluminum alloys[J]. Materials Review, 2010, 24 (5): 132-137.
[3] Tang H, Sun Q, Xin T, et al. Influence of Co(CH3COO)2 concentration on thermal emissivity of coatings formed on titanium alloy by micro-arc oxidation[J]. Current Applied Physics, 2012, 12(1): 284-290.
[4] 林修洲, 郑健峰, 林志君, 等. TC4钛合金微弧氧化涂层的制备与微动 磨损性能研究[J]. 航空材料学报, 2009, 29(2): 43-47. Lin Xiuzhou, Zheng Jianfeng, Lin Zhijun, et al. Preparation and fretting wear performance of microarc oxidation coating on TC4 titanium alloy [J]. Journal of Aeronautical Materials, 2009, 29(2): 43-47.
[5] 崔丽, 栗桌新, 魏琪. 高温氧化对钛合金超塑性能的影响[J]. 钛工业进 展, 2006, 23(2): 21-24. Cui Li, Li Zhuoxin, Wei Qi. Effect of high temperature oxidation on titanium alloy super plastic properties[J]. Titanium Industry Progress, 2006, 23(2): 21-24.
[6] 廖强, 杜楠, 赵晴, 等. 化学复合镀镍-磷-金刚石的工艺及性能的研 究[J]. 材料工程,2006(增1): 334-337. Liao Qiang, Du Nan, Zhao Qing, et al. Study on process and performance of electroless composite plating of nickel- phosphorusdiamond[ J]. Material Engineering, 2006(Suppl 1): 334-337.
[7] Garcia I, Fransaer J, Celis J P. Electrodeposition and sliding wear resistance of nickel composite coatings containing micron and submicron SiC particles[J]. Surface and Coatings Technology, 2001, 148(2): 171-178.
[8] Zhao G G, Zhou Y, Zhang H. Sliding wear behaviors of electrodeposited Ni composite coatings containing micrometer and nanometer Cr particles [J]. Transactions of Nonferrous Metals Society of China, 2009, 19(2): 319-323.
[9] 黄丹, 张晓燕, 吴德峰. 纳米α-Al2O3添加剂对铝合金微弧氧化膜层性 能的影响[J]. 表面技术, 2014, 43(4): 43-47. Huang Dan, Zhang Xiaoyan, Wu Defeng. Effects of Nano α- Al2O3 additive on the performance of micro-arc oxidation coating formed on aluminum alloy[[J]. Surface Technology, 2014, 43(4): 43-47.
[10] 李均明. 铝合金微弧氧化陶瓷层的形成机制及其磨损性能[D]. 西 安: 西安理工大学, 2008. Li Junming. Formation mechanism and abrasion tests of micro-arc oxidation ceramic layers on aluminum alloy[D]. Xi'an: Xi'an University of Science and Technology, 2008.
[11] 杨双燕. 铝合金微弧氧化厚膜工艺研究[D]. 南京: 南京理工大学, 2012. Yang Shuangyan. General survey of the research on micro-arc oxidation process of aluminum alloys[D]. Nanjing: Nanjing University of Science and Technology, 2012.
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