专题论文

基于嵌段共聚物自组装制备Janus纳米粒子的研究进展

  • 刘善芹 ,
  • 张毅军 ,
  • 邓仁华 ,
  • 梅路平
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  • 1. 河南科技学院化学化工学院, 新乡 453003;
    2. 中国科学院化学研究所, 北京 100190;
    3. 海洋石油工程股份有限公司, 天津 300451
刘善芹,讲师,研究方向为微流控与聚合物微球材料

收稿日期: 2015-08-15

  修回日期: 2015-11-10

  网络出版日期: 2016-02-04

基金资助

河南省科技攻关重点项目(092102310227)

Progress in preparation of Janus nanoparticles by self-assembly of block copolymers

  • LIU Shanqin ,
  • ZHANG Yijun ,
  • DENG Renhua ,
  • MEI Luping
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  • 1. School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;
    2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
    3. Offshore Oil Engineering Co., Ltd., Tianjin 300451, China

Received date: 2015-08-15

  Revised date: 2015-11-10

  Online published: 2016-02-04

摘要

Janus 粒子的两面具有不同的组成或性质,在乳液稳定、药物载体、界面催化及超结构的构筑等方面有着重要应用价值。尤其是基于嵌段共聚物的Janus 纳米粒子,其两面的聚合物链通过共价键相连,结构非常稳定。由于其纳米尺度和柔性及对溶剂、温度、pH 值等外部刺激具有响应性,嵌段共聚物Janus 纳米粒子备受关注。实现嵌段共聚物Janus 纳米粒子形貌和结构可控、组成多样化及批量化制备是该研究的重点和难点。本文综述嵌段共聚物自组装制备Janus 纳米粒子的方法,比较了不同方法的特点及适用范围。

本文引用格式

刘善芹 , 张毅军 , 邓仁华 , 梅路平 . 基于嵌段共聚物自组装制备Janus纳米粒子的研究进展[J]. 科技导报, 2016 , 34(2) : 27 -32 . DOI: 10.3981/j.issn.1000-7857.2016.2.002

Abstract

The Janus particles of two compositions or properties distinctly compartmentalized have important applications in stabilizing emulsion, drug carriers, interfacial catalysis, and building superstructures. Especially, the Janus nanoparticles of block copolymers with covalently linked compartments are strong in structure, and have attracted growing interests due to their nano-size, the flexible structures, and the response to solvent, pH value, temperature or other stimuli. It is important to develop new methods for a large-scale synthesis of Janus nanoparticles with tunable morphology, structure and chemical composition. This review summarizes the recent progress in the preparation of block copolymer Janus nanoparticles. Some important methods are discussed and compared in detail, which is conducive to the design and the preparation of the Janus nanoparticles for potential applications.

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