刘瑞刚 , 徐坚 . 国产高性能聚丙烯腈基碳纤维制备技术研究进展[J]. 科技导报, 2018 , 36(19) : 32 -42 . DOI: 10.3981/j.issn.1000-7857.2018.19.006

[1] Liang H W, Liu J W, Qian H S, et al. Multiplex templating process in one-dimensional nanoscale:Controllable synthesis, macroscopic assemblies, and applications[J]. Accounts of Chemical Research, 2013; 46(7):1450-1461.
[2] Liang H W, Guan Q F, Chen L F, et al. Macroscopic-scale template synthesis of robust carbonaceous nanofiber hydrogels and aerogels and their applications[J]. Angewandte Chemie-International Edition, 2012, 51(21):5101-5105.
[3] Chen L F, Huang Z H, Liang H W, et al. Flexible all-solidstate high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose[J]. Energy & Environmental Science, 2013, 6(11):3331-3338.
[4] Liang H W, Guan Q F, Zhu Z, et al. Highly conductive and stretchable conductors fabricated from bacterial cellulose[J]. Npg Asia Materials, 2012, 4(6):e19.
[5] Chen L F, Zhang X D, Liang H W, et al. Synthesis of nitrogendoped porous carbon nanofibers as an efficient electrode material for supercapacitors[J]. ACS Nano, 2012, 6(8):7092-7102.
[6] Liang H W, Cao X, Zhang W J, et al. Robust and highly efficient free-standing carbonaceous nanofiber membranes for water purification[J]. Advanced Functional Materials, 2011, 21(20):3851-3858.
[7] Chen P, Liang H W, Lü X H, et al. Carbonaceous nanofiber membrane functionalized by beta-cyclodextrins for molecular filtration[J]. ACS Nano, 2011, 5(7):5928-5935.
[8] Liang H W, Zhang W J, Ma Y N, et al. Highly active carbonaceous nanofibers:A versatile scaffold for constructing multifunctional free-standing membranes[J]. ACS Nano, 2011, 5(10):8148-8161.
[9] Liang H W, Wang L, Chen P Y, et al. Carbonaceous nanofiber membranes for selective filtration and separation of nanoparticles[J]. Advanced Materials, 2010, 22(42):4691-4695.
[10] Wu Z Y, Li C, Liang H W, et al. Ultralight, flexible, and fireresistant carbon nanofiber aerogels from bacterial cellulose[J]. Angewandte Chemie-International Edition, 2013, 52(10):2925-2929.
[11] Chen L F, Huang Z H, Liang H W, et al. Bacterial-cellulosederived carbon nanofiber@MnO₂ and nitrogen-doped carbon nanofiber electrode materials:An asymmetric supercapacitor with high energy and power density[J]. Advanced Materials, 2013, 25(34):4746-4752.
[12] Frank E, Steudle L M, Ingildeev D, et al. Carbon fibers:Precursor systems, processing, structure, and properties[J]. Angewandte Chemie-International Edition, 2014, 53(21):5262-5298.
[13] Li Q, Xie S X, Serem W K, et al. Quality carbon fibers from fractionated lignin[J]. Green Chemistry, 2017, 19(7):1628-1634.
[14] Li Q, Ragauskas A J, Yuan J S. Lignin carbon fiber:The path for quality[J]. Tappi Journal, 2017, 16(3):107-108.
[15] Steudle L M, Frank E, Ota A, et al. Carbon fibers prepared from melt spun peracylated softwood lignin:An integrated approach[J]. Macromolecular Materials and Engineering, 2017, 302(4):1700195.
[16] Barton B E, Behr M J, Patton J T, et al. High-modulus lowcost carbon fibers from polyethylene enabled by boron catalyzed graphitization[J]. Small, 2017, 13(36):1701926.
[17] Behr M J, Landes B G, Barton B E, et al. Structure-property model for polyethylene-derived carbon fiber[J]. Carbon, 2016, 107:525-535.
[18] Kim K W, Lee H M, An J H, et al. Effects of cross-linking methods for polyethylene-based carbon fibers:Review[J]. Carbon Letters, 2015, 16(3):147-170.
[19] Younker J M, Saito T, Hunt M A, et al. Pyrolysis pathways of sulfonated polyethylene, an alternative carbon fiber precursor[J]. Journal of the American Chemical Society, 2013, 135(16):6130-6141.
[20] Dalton S, Heatley F, Budd P M. Thermal stabilization of polyacrylonitrile fibres[J]. Polymer, 1999, 40(20):5531-5543.
[21] Ouyang Q, Cheng L, Wang H J, et al. Mechanism and kinetics of the stabilization reactions of itaconic acid-modified polyacrylonitrile[J]. Polymer Degradation and Stability, 2008, 93(8):1415-1421.
[22] Watt W, Johnson W. Mechanism of oxidization of polyacrylonitrile fibers[J]. Nature, 1975, 257(5523):210-212.
[23] Nunna S, Naebe M, Hameed N, et al. Evolution of radial heterogeneity in polyacrylonitrile fibres during thermal stabilization:An overview[J]. Polymer Degradation and Stability, 2017, 136:20-30.
[24] Grassie N, McGuchan R. Pyrolysis of polyacrylonitrile and related polymer-VⅢ. Copolymers of acrylonitrile with vinylacetate, vinyl formate, acrolein and methyl vinyl ketone[J]. European Polymer Journal, 1973, 9(2):113-124.
[25] Grassie N, McGuchan R. Pyrolysis of polyacrylonitrile and related polymers-Ⅱ Effect of sample preparation on thermal behaviour of polyacrylonitrile[J]. European Polymer Journal, 1971, 7(8):1091-1104.
[26] Grassie N, McGuchan R. Pyrolysis of polyacrylonitrile and related polymers-VI. Acrylonitrile copolymers containing carboxylic-acid and amide structures[J]. European Polymer Journal, 1972; 8(2):257-269.
[27] 李悦生, 李百祥, 张贵宝, 等. 一种链结构均匀的丙烯腈二元共聚物纺丝液及制备方法:CN101413153A[P]. 2009-04-22. Li Yuesheng, Li Baixiang, Zhang Guibao, et al. Acrylonitrile biopolymer spinning fluid having homogeneous chain structure and preparation thereof:CN101413153A[P]. 2009-04-22.
[28] Liu X F, Zhu C Z, Dong H X, et al. Effect of microgel content on the shear and extensional rheology of polyacrylonitrile solution[J]. Colloid and Polymer Science, 2015, 293(2):587-596.
[29] 徐坚, 刘瑞刚. 高性能纤维基本科学原理[M]. 北京:国防工业出版社, 2018. Xu Jian, Liu Ruigang. Fundamentals of high performance fibers[M]. Beijing:National Defense Industry Press, 2018.
[30] 余晓兰. 聚丙烯腈基材料的制备、表征及应用[D]. 北京:中国科学院化学研究所, 2011. Yu Xiaolan. The preparation, characterization, and applications of polyacrylnitril based materials[D]. Beijing:Institute of Chemistry, Chinese Academy of Sciences, 2011.
[31] 刘小芳. 聚丙烯腈溶胶-凝胶转变及其纤维结构演变的研究[D]. 北京:中国科学院化学研究所, 2014. Liu Xiaofang. Researches on the sol-gel transition of polyacrylnitril solution and the structure formation and development of polyacrylnitril fibers[D]. Beijing:Institute of Chemistry, Chinese Academy of Sciences, 2014.
[32] Marinesco S, Carew T J. Improved electrochemical detection of biogenic amines in Aplysia using base-hydrolyzed cellulose-coated carbon fiber microelectrodes[J]. Journal of Neuroscience Methods, 2002, 117(1):87-97.
[33] Ko T H. Influence of continuous stabilization on the physicalproperties and microstructure of PAN-based carbon-fibers[J]. Journal of Applied Polymer Science, 1991, 42(7):1949-1957.
[34] Huang X S. Fabrication and properties of carbon fibers[J]. Materials, 2009, 2(4):2369-2403.
[35] Sedghi A, Farsani R E, Shokuhfar A. The effect of commercial polyacrylonitrile fibers characterizations on the produced carbon fibers properties[J]. Journal of Materials Processing Technology, 2008, 198(1/2/3):60-67.
[36] Dunham M G, Edie D D. Model of stabilization for PANbased carbon-fiber precursor bundles[J]. Carbon, 1992, 30(3):435-450.
[37] Houtz R C. "Orlon" acrylic fiber:Chemistry and properties[J]. Textile Research Journal, 1950, 20(11):786-801.
[38] Schurz J. Discoloration effects in acrylonitrile polymers[J]. Journal of Polymer Science, 1958, 28(117):438-439.
[39] Standage A E, Matkowsky R D. Thermal oxidation of polyacrylonitrile[J]. European Polymer Journal, 1971, 7(7):775-783.
[40] Friedlander H N, Peebles L H, Brandrup J, et al. On the chromophore of polyacrylonitrile. VI. Mechanism of color formation in polyacrylonitrile[J]. Macromolecules, 1968, 1(1):79-86.
[41] Henrici-Olivé G, Olivé S. Molecular interactions and macroscopic properties of polyacrylonitrile and model substances[M]//Chemistry. Berlin, Heidelberg:Springer Berlin Heidelberg, 1979:123-152.
[42] Ganster J, Fink H P, Zenke I. Chain conformation of polyacrylonitrile-A comparison of model scattering and radial-distribution functions with experimental wide-angle X-ray-scattering results[J]. Polymer, 1991; 32(9):1566-1573.
[43] Gupta A, Harrison I R. New aspects in the oxidative stabilization of PAN-based carbon fibers:Ⅱ[J]. Carbon, 1997, 35(6):809-818.
[44] Gupta A, Harrison I R. New aspects in the oxidative stabilization of PAN-based carbon fibers[J]. Carbon, 1996, 34(11):1427-1445.
[45] Liu X R, Chen W, Hong Y L, et al. Stabilization of atacticpolyacrylonitrile under Nitrogen and air as studied by solidstate NMR[J]. Macromolecules, 2015, 48(15):5300-5309.
[46] Liu X R, Makita Y, Hong Y L, et al. Chemical reactions and their kinetics of atactic-polyacrylonitrile as revealed by solidstate ¹³C NMR[J]. Macromolecules, 2017, 50(1):244-253.
[47] Wang Y S, Xu L H, Wang M Z, et al. Structural identification of polyacrylonitrile during thermal treatment by selective ¹³C labeling and solid-state ¹³C NMR spectroscopy[J]. Macromolecules, 2014, 47(12):3901-3908.
[48] Layden G K. Retrograde core formation during oxidation of polyacrylonitrile filaments[J]. Carbon, 1972, 10(1):59-60.
[49] Liu X F, Zhu C Z, Guo J, et al. Nanoscale dynamic mechanical imaging of the skin-core difference:From PAN precursors to carbon fibers[J]. Materials Letters, 2014, 128:417-420.
[50] Lian F, Liu J, Ma Z K, et al. Stretching-induced deformation of polyacrylonitrile chains both in quasicrystals and in amorphous regions during the in situ thermal modification of fibers prior to oxidative stabilization[J]. Carbon, 2012, 50(2):488-499.
[51] Fitzer E, Frohs W, Heine M. Optimization of stabilization and carbonization treatment of PAN fibers and structural characterization of the resulting carbon-fibers[J]. Carbon, 1986, 24(4):387-395.