综述

低温等离子体脱硫技术研究进展

  • 夏诗杨 ,
  • 马文鑫 ,
  • 米俊锋 ,
  • 杜胜男 ,
  • 杨爽 ,
  • 于靖尚
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  • 1. 辽宁石油化工大学土木工程学院, 抚顺 113001;
    2. 中国昆仑工程有限公司沈阳分公司, 沈阳 110000;
    3. 辽宁石油化工大学石油天然气工程学院, 抚顺 113001;
    4. 中国石油天然气股份有限公司辽河油田分公司供水公司, 盘锦 124010;
    5. 辽宁石油化工大学创新创业学院, 抚顺 113001
夏诗杨,硕士研究生,研究方向为低温等离子体与气体污染控制工程,电子信箱:1194150360@qq.com

收稿日期: 2020-03-11

  修回日期: 2021-08-25

  网络出版日期: 2022-08-05

基金资助

国家自然科学基金项目(20277004)

Research progress of non-thermal plasma desulfurization technology

  • XIA Shiyang ,
  • MA Wenxin ,
  • MI Junfeng ,
  • DU Shengnan ,
  • YANG Shuang ,
  • YU Jingshang
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  • 1. College of Petroleum Engineering,Liaoning Shihua University, Fushun 113001, China;
    2. ShenyangBranch, China Kunlun Engineering Company Limited, Shenyang 110000, China;
    3. College of Petroleum and Natural Gas Engineering, Liaoning Shihua University, Fushun 113001, China;
    4. Water Supply Company, Liaohe Oil field Branch, China National Petroleum, Panjin 124010, China;
    5. College of Innovation and Entrepreneurship, Liaoning Shihua University, Fushun 113001, China

Received date: 2020-03-11

  Revised date: 2021-08-25

  Online published: 2022-08-05

摘要

SO2气体排量大、污染重,传统的脱硫技术存在经济、技术等方面局限,而低温等离子体技术用于净化污染气体具有脱除效率高、适用性广等优点。介绍了电子束、电晕放电、介质阻挡放电3种低温等离子体技术脱除SO2的研究进展,分析了其技术机理、影响因素,并讨论了低温等离子体脱硫技术的可能研究趋势。

本文引用格式

夏诗杨 , 马文鑫 , 米俊锋 , 杜胜男 , 杨爽 , 于靖尚 . 低温等离子体脱硫技术研究进展[J]. 科技导报, 2022 , 40(12) : 66 -72 . DOI: 10.3981/j.issn.1000-7857.2022.12.006

Abstract

Aiming at the effective treatment of SO2 gas with wide range, large displacement, and heavy pollution, the traditional desulfurization technology has economic and technical limitations, while non-thermal plasma technology has the advantages of high removal efficiency, and wide applicability for purifying polluted gases, and has received extensive attention and research.. The article introduces the research progress of three non-thermal plasma technologies removal of SO2 by electron beam, corona discharge, and dielectric barrier discharge. The technical mechanism and influencing factors are reviewed, and possible research trends of non-thermal plasma desulfurization technology are analyzed.

参考文献

[1] 苑贺楠,何广湘,孔令通,等.工厂燃煤烟气脱硫技术进展[J].工业催化, 2019, 27(9):8-12.
[2] 刘睿劼,张智慧.中国工业二氧化硫排放趋势及影响因素研究[J].环境污染与防治, 2012, 34(10):100-104.
[3] Carletti C, Henrik G, Blasio C D, et al. Limestone dissolution study for wet flue gas desulfurization under turbulent regimes above critical suspension speed[J]. Computer Aided Chemical Engineering, 2013, 32(1):301-306.
[4] 杨忠凯,王敬臣,武宁,等.燃煤烟气脱硫技术综述[J].河南化工, 2019, 36(3):7-10.
[5] Cui S, Hao R L, Fu D. An integrated system of dielectric barrier discharge combined with wet electrostatic precipitator for simultaneous removal of NO and SO2:Key factors assessments, products analysis and mechanism[J]. Fuel, 2018, 221:12-20.
[6] Ma S, Zhao Y, Yang J, et al. Research progress of pollutants removal from coal-fired flue gas using non-thermal plasma[J]. Renewable and Sustainable Energy Reviews, 2017, 67:791-810.
[7] Schiavon M, Torretta V, Casazza A, et al. Non-thermal plasma as an innovative option for the Abatement of volatile organic compounds:A Review[J]. Water, Air & Soil Pollution, 2017, 228(10):388-407.
[8] 史亚微.不同供电方式下等离子体脱除烟气中SO2及颗粒物的研究[D].北京:华北电力大学环境科学与工程学院, 2011.
[9] Huang L, Xia L Y, Ge X X, et al. Removal of H2S from gas stream using combined plasma photolysis technique at atmospheric pressure[J]. Chemosphere, 2012, 88(2):229-234.
[10] Ighigeanu D, Martin D, Zisslescu E, et al. SO2 and NOx removal by electron beam and electrical discharge induced non-thermal plasmas[J]. Vacuum, 2005, 77(4):493-500.
[11] 宁平,徐可,王学谦,等.低温等离子体技术处理含硫恶臭气体的研究进展[J].材料导报, 2015, 29(21):66-71.
[12] 李盼宋,李建军,贺尧祖,等.电子束氨法协同脱硫脱硝技术的研究进展[J].四川化工, 2016, 19(1):13-15.
[13] Hong L, Chen D Z, Yang M, et al. Interaction between NO and SO2 removal processes in a pulsed corona discharge plasma (PCDP) reactor and the mechanism[J]. Chemical Engineering Journal, 2019, 359:1130-1138.
[14] Zhou Y, Deng Y, Wu P, et al. The effects of ventilation and floor heating systems on the dispersion and deposition of fine particles in an enclosed environment[J]. USA:Building and Environment, 2017, doi:10.1016/j. buildenv.2017.08.049.
[15] Park J H, Ahn J W, Kim K H, et al. Historic and futuristic review of electronbeam technology for the treatment of SO2 and NOx in flue gas[J]. Chemical Engineering Journal, 2018, doi:10.1016/j.cej.2018.08.103.
[16] Gogulancea V, Lavric V. Flue gas cleaning by high energy electron beam-Modeling and sensitivity analysis[J]. Applied Thermal Engineering, 2014, 70(2):1253-1261.
[17] Chmielewski A G. Industrial applications of electron beam flue gas treatment-from laboratory to the practice[J]. Radiation Physics and Chemistry, 2007, 76(8-9):1480-1484.
[18] Yong K K, Do H H. Microwave effect in the simultaneous removal of NOx and SO2 under rlectron beam irradiation and kinetic investigation of NOx removal rate[J]. Industrial&Engineering Chemistry Research, 2010, 49(17):8147-8156.
[19] Basfar A A, Fageeha O I, Kunnummal N, et al. Electron beam flue gas treatment (EBFGT) technology for simultaneous removal of SO2 and NOx from combustion of liquid fuels[J]. Fuel, 2008, 87(8/9):1446-1452.
[20] Licki J, Chmielewski A G, Zimek Z, et al. Electron beam process for SO2 removal from flue gases with high SO2 content[J]. Radiation Physics and Chemistry, 2002, 63(3-6):637-639.
[21] Radoiu M T, Martin D I, Calinescu I. Emission control of SO2 and NOx by irradiation methods[J]. Journal of Hazardous Materials, 2003, 97(1-3):145-158.
[22] Akria M. Generation of non-thermal plasma combined with catalysts and their application in environmental technology[J]. Catalysis Today, 2013, 211(Complete):2-8.
[23] Yimin Z, Chae J O, Kim K Y, et al. Effects of Water Vapor and Ammoniaon SO2 removal from flue gases using pulsed corona discharge[J]. Plasma Chemistry and Plasma Processing, 2002, 22(1):187-195.
[24] Eliasson B, Kogelschatz U. Nonequilibrium volume plasmachemical processin[J]. IEEE Transactions on PlasmaScience, 1992, 19(6):1063-1077.
[25] 王祖武,曾汉才,梅欢,等.放电电场对SO2气相传质过程的影响[J].中国电机工程学报, 2006, 26(4):23-26.
[26] Moka Y S, Namb I S. Modeling of pulsed corona discharge process for the removal of nitric oxide and sulfur dioxide[J]. Chemical Engineering Journal, 2002, 85(1):87-97.
[27] Wang Z W, Zeng H C, Guo J, et al. Sulfur dioxide (SO2) gas transfer process enhanced by corona discharge[J]. Journal of Electrostatics, 2007, 65(8):485-489.
[28] Xu F, Liu Y Z, Cui W, et al. Simultaneous oxidation of NO, SO2 and HgO from flue gasby pulsed corona discharge[J]. Journal of Environmental Sciences, 2009, 21(3):328-332.
[29] 曹玮,骆仲泱,徐飞,等.脉冲电晕放电协同烟气脱硫脱硝试验研究[J].环境科学学报, 2008, 28(12):2487-249.
[30] Yu C J, Xu F, Luo Z Y, et al. Influences of water vapor and fly ash addition on NO and SO2 gas conversion efficiencies enhanced by pulsed corona discharge[J]. Journal of Electrostatics, 2009, 67(6):829-834.
[31] Sum M, Wu Y. Removal of SO2 from flue gas by water vapor DC corona discharge[J]. Environmental Science, 2006, 27(7):1282-1285.
[32] 方志,邱毓昌,王辉,等.介质阻挡放电的电荷传输特性研究[J].高压电, 2004, 40(6):401-403.
[33] 孙岩洲,邱毓昌,袁兴成.介质阻挡电晕放电去除二氧化硫的研究[J].高压电器, 2004, 40(4):253-258.
[34] Ma H B, Chen P, Zhang M L, et al. Study of SO2 removal using non-thermal plasma induced by dielectric barrier discharge[J]. Plasma Chemistry and Plasma Processing, 2002, 22(2):239-253.
[35] Bai M, Leng B, Mao S, et al. Flue gas desulfurization by dielectric barrier discharge[J]. Plasma Chemistry and Plasma Processing, 2016, 36(2):511-521.
[36] Obradovi B M, Sretenovi G B, Kuraica M M. A dual-use of DBD plasma for simultaneous NOx and SO2 removal from coal-combustion flue gas[J]. Journal of Hazardous Materials, 2011, 185(2/3):1280-1286.
[37] 赵之骏,吴玉萍,张仁熙,等.高频介质阻挡放电烟气脱硫研究[J].化学学报, 2004, 62(2-3):28-32.
[38] 张俊杰,任建兴,李芳芹,等.介质阻挡放电低温等离子体脱硫脱硝过程的研究[J].应用化工, 2018, 47(1):109-112.
[39] 王雪涛,王沛迪,刘予,等.介质阻挡放电脱硫效率影响因素试验研究[J].热力发电, 2016, 45(3):59-63.
[40] Cui S P, Hao R L, Fu D. Integrated method of non-thermalplasma combined with catalytical oxidation for simultaneous removal of SO2 and NO[J]. Fuel, 2019, 246:365-374.
[41] 李海玮,王祖武,李萍.介质阻挡放电同时脱硫脱硝中放电特性研究[J].环境科学与技术, 2015, 38(Suppl1):88-91.
[42] Nasonova A, Pham H C, Kim D J, et al. NO and SO2 removal in non-thermal plasma reactor packed with glass beads-TiO2 thin film coated by PCVD process[J]. Chemical Engineering Journal, 2010, 156(3):557-561.
[43] 郭彬,栾涛.介质阻挡放电低温等离子体脱硝性能研究[J].核聚变与等离子体物理, 2017, 37(2):236-243.
[44] Kogelschatz U. Dielectric barrier discharges:Their history, discharge physics, and industrial applications[J]. Plasma Chem Plasma Process, 2003, 23(1):1-46.
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