专题:新污染物治理

城镇污水厂新污染物赋存特征及去除技术研究进展

  • 封涛涛 ,
  • 王斌 ,
  • 李江 ,
  • 王涛 ,
  • 许晓毅 ,
  • 侯立安
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  • 1. 贵州大学土木工程学院, 贵阳 550025;
    2. 浙江大学化学工程与生物工程学院, 杭州 310027;
    3. 贵州大学资源与环境工程学院, 贵阳 550025;
    4. 苏州科技大学环境科学与工程学院, 苏州 215009;
    5. 中国人民解放军96901部队23分队, 北京 100094
封涛涛,硕士研究生,研究方向为水环境中新污染物治理,电子信箱:1271440586@qq.com;王斌(通信作者),特聘教授,研究方向为水中新污染物治理,电子信箱:bwang7@gzu.edu.cn;侯立安(共同通信作者),中国工程院院士,正高级工程师,研究方向为饮用水安全保障、分散点源生活污水处理等,电子信箱:h20091957@126.com

收稿日期: 2024-01-04

  修回日期: 2024-04-28

  网络出版日期: 2024-07-08

基金资助

国家自然科学基金项目(22306037,52360012);贵州省科技计划项目(QKHZC[2023]YB110,QKHJC-ZK[2022]YB102);贵州大学自然科学专项(特岗)科研基金项目(X2021003)

Research progress on occurrence characteristics and removal technologies of emerging contaminants in urban sewage treatment plants

  • FENG Taotao ,
  • WANG Bin ,
  • LI Jiang ,
  • WANG Tao ,
  • XU Xiaoyi ,
  • HOU Li'an
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  • 1. College of Civil Engineering, Guizhou University, Guiyang 550025, China;
    2. Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    3. College of Resources and Environmental Engineering, Guizhou University, Guiyang 550025, China;
    4. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China;
    5. Detachment 23, Unit 96901 People's Liberation Army of China, Beijing 100094, China

Received date: 2024-01-04

  Revised date: 2024-04-28

  Online published: 2024-07-08

摘要

城镇污水处理厂作为新污染物的重要源和汇,是控制新污染物排放的关键屏障。城镇污水中新污染物赋存特征相关研究发现,不同地区污水中新污染物浓度呈现出明显的地域特征,主要与区域环境条件、服务区域人口密度、污水来源、社会经济状况和产业布局等因素密切相关;解析了新污染物在城镇污水处理厂各单元的迁移转化规律,明晰了污水处理厂新污染物去除受污水处理工艺、新污染物种类等关键因子影响;阐明了目前城镇污水处理厂去除新污染物面临法规标准空白、监测技术短板明显、风险评估体系建设难度大、去除技术时效性低等挑战,并提出了相应防控对策。

本文引用格式

封涛涛 , 王斌 , 李江 , 王涛 , 许晓毅 , 侯立安 . 城镇污水厂新污染物赋存特征及去除技术研究进展[J]. 科技导报, 2024 , 42(11) : 36 -46 . DOI: 10.3981/j.issn.1000-7857.2024.01.00018

Abstract

Urban wastewater treatment plants are important sinks and sources of emerging contaminants, which are a crucial barrier to interrupt its discharge into the aquatic environment. To provide ideas for the prevention and control of emerging contaminants in urban wastewater treatment plants and help achieve the construction of a healthy China, this paper focuses on the categories of emerging contaminants in urban wastewater. We argue that the concentrations of emerging contaminants in wastewater from different districts show significant geographical characteristics, which are closely related to regional environmental conditions, population density, wastewater sources, socio-economic conditions and industrial layout. We analyze the migration and transformation patterns of emerging contaminants in various units of urban wastewater treatment plants. The results indicate that removal of emerging contaminants from wastewater treatment plants is influenced by critical factors including wastewater treatment processes and emerging contaminants categories. We also illustrate that removal of emerging contaminants from urban wastewater treatment plants is currently challenged by the lack of regulations and standards, outdated monitoring technologies, hard-to-construct risk assessment systems, and ineffective removal technologies. We propose appropriate prevention and control strategies to address these challenges.

参考文献

[1] 李江蕴.我国新污染物治理现状与对策[J].质量与认证, 2023(7):81-83.
[2] Guo J, Tu K, Chou L B, et al. Deep mining of reported emerging contaminants in China's surface water in the past decade:Exposure, ecological effects and risk assess-ment[J]. Water Research, 2023, 243:120318.
[3] Rizzo L, Malato S, Antakyali D, et al. Consolidated vs new advanced treatment methods for the removal of con-taminants of emerging concern from urban wastewater[J]. The Science of the Total Environment, 2019, 655:986-1008.
[4] Tran N H, Reinhard M, Gin K Y H. Occurrence and fate of emerging contaminants in municipal wastewater treat-ment plants from different geographical regions-A review[J]. Water Research, 2018, 133:182-207.
[5] Liu J C, Yang F, Cai Y F, et al. Unveiling the existence and ecological hazards of trace organic pollutants in wastewater treatment plant effluents across China[J]. EcoEnvironment&Health, 2024, 3(1):21-29.
[6] Giri A, Pant D, Chandra Srivastava V, et al. Plant-mi-crobe assisted emerging contaminants (ECs) removal and carbon cycling[J]. Bioresource Technology, 2023, 385:129395.
[7] Li S Q, Zhu Y, Zhong G B, et al. Comprehensive assess-ment of environmental emissions, fate, and risks of veteri-nary antibiotics in China:An environmental fate modeling approach[J]. Environmental Science&Technology, 2024, 58(12):5534-5547.
[8] Ismanto A, Hadibarata T, Kristanti R A, et al. Endocrine disrupting chemicals (EDCs) in environmental matrices:Occurrence, fate, health impact, physio-chemical and bio-remediation technology[J]. Environmental Pollution, 2022, 302:119061.
[9] Bilal M, Adeel M, Rasheed T, et al. Emerging contami-nants of high concern and their enzyme-assisted biodegra-dation:A review[J]. Environment International, 2019, 124:336-353.
[10] Zhang L R, Zhu Z, Zhao M L, et al. Occurrence, remov-al, emission and environment risk of 32 antibiotics and metabolites in wastewater treatment plants in Wuhu, Chi-na[J]. The Science of the Total Environment, 2023, 899:165681.
[11] Li P, Wang Y R, Huang B, et al. Antibiotics in wastewa-ter of Guangdong, China:Distribution patterns, and their environmental risk due to incomplete removal[J]. The Science of the Total Environment, 2022, 849:157889.
[12] Ashfaq M, Li Y, Wang Y W, et al. Occurrence, fate, and mass balance of different classes of pharmaceuticals and personal care products in an anaerobic-anoxic-oxic wastewater treatment plant in Xiamen, China[J]. Water Research, 2017, 123:655-667.
[13] Sun C S, Hu E, Liu S W, et al. Spatial distribution and risk assessment of certain antibiotics in 51 urban waste-water treatment plants in the transition zone between North and South China[J]. Journal of Hazardous Materi-als, 2022, 437:129307.
[14] Liu J, Ge S M, Shao P, et al. Occurrence and removal rate of typical pharmaceuticals and personal care prod-ucts (PPCPs) in an urban wastewater treatment plant in Beijing, China[J]. Chemosphere, 2023, 339:139644.
[15] Mu H X, Li J H, Chen L, et al. Distribution, source and ecological risk of per-and polyfluoroalkyl substances in Chinese municipal wastewater treatment plants[J]. Envi-ronment International, 2022, 167:107447.
[16] Li W H, Shi Y L, Gao L H, et al. Occurrence and re-moval of antibiotics in a municipal wastewater reclama-tion plant in Beijing, China[J]. Chemosphere, 2013, 92(4):435-444.
[17] Zhao H, Cao Z, Liu X, et al. Seasonal variation, flux esti-mation, and source analysis of dissolved emerging organ-ic contaminants in the Yangtze Estuary, China[J]. Ma-rine Pollution Bulletin, 2017, 125(1/2):208-215.
[18] Liu X H, Zhang G D, Liu Y, et al. Occurrence and fate of antibiotics and antibiotic resistance genes in typical urban water of Beijing, China[J]. Environmental Pollu-tion, 2019, 246:163-173.
[19] Chandel N, Ahuja V, Gurav R, et al. Progress in microal-gal mediated bioremediation systems for the removal of antibiotics and pharmaceuticals from wastewater[J]. The Science of the Total Environment, 2022, 825:153895.
[20] Oberoi A S, Jia Y Y, Zhang H Q, et al. Insights into the fate and removal of antibiotics in engineered biological treatment systems:A critical review[J]. Environmental Science&Technology, 2019, 53(13):7234-7264.
[21] Tiwari B, Sellamuthu B, Ouarda Y, et al. Review on fate and mechanism of removal of pharmaceutical pollutants from wastewater using biological approach[J]. Bioresource Technology, 2017, 224:1-12.
[22] 郑兴灿,张昱,贲伟伟,等.城镇污水微量新污染物赋存特征与全过程控制技术研究[J].给水排水, 2022, 58(6):26-34.
[23] Lasaki B A, Maurer P, Schönberger H, et al. Empower-ing municipal wastewater treatment:Enhancing particu-late organic carbon removal via chemical advanced pri-mary treatment[J]. Environmental Technology&Innova-tion, 2023, 32:103436.
[24] Stasinakis A S, Thomaidis N S, Arvaniti O S, et al. Con-tribution of primary and secondary treatment on the re-moval of benzothiazoles, benzotriazoles, endocrine dis-ruptors, pharmaceuticals and perfluorinated compounds in a sewage treatment plant[J]. The Science of the Total Environment, 2013, 463/464:1067-1075.
[25] Luo Y L, Guo W S, Ngo H H, et al. A review on the oc-currence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment[J]. The Science of the Total Environment, 2014, 473/474:619-641.
[26] Saidulu D, Gupta B, Gupta A K, et al. A review on oc-currences, eco-toxic effects, and remediation of emerging contaminants from wastewater:Special emphasis on bio-logical treatment based hybrid systems[J]. Journal of Envi-ronmental Chemical Engineering, 2021, 9(4):105282.
[27] Rout P R, Zhang T C, Bhunia P, et al. Treatment tech-nologies for emerging contaminants in wastewater treat-ment plants:A review[J]. The Science of the Total Envi-ronment, 2021, 753:141990.
[28] Tran N H, Gin K Y H. Occurrence and removal of phar-maceuticals, hormones, personal care products, and en-docrine disrupters in a full-scale water reclamation plant[J]. The Science of the Total Environment, 2017, 599/600:1503-1516.
[29] Langbehn R K, Michels C, Soares H M. Antibiotics in wastewater:From its occurrence to the biological remov-al by environmentally conscious technologies[J]. Environ-mental Pollution, 2021, 275:116603.
[30] Stadler L B, Su L J, Moline C J, et al. Effect of redox conditions on pharmaceutical loss during biological wastewater treatment using sequencing batch reactors[J]. Journal of Hazardous Materials, 2015, 282:106-115.
[31] Nguyen P Y, Carvalho G, Reis M A M, et al. A review of the biotransformations of priority pharmaceuticals in biological wastewater treatment processes[J]. Water Re-search, 2021, 188:116446.
[32] Carneiro R B, Gonzalez-Gil L, Londoño Y A, et al. Ac-idogenesis is a key step in the anaerobic biotransforma-tion of organic micropollutants[J]. Journal of Hazardous Materials, 2020, 389:121888.
[33] Wang X C, Chen Z L, Shen J M, et al. Effect of carbon source on pollutant removal and microbial community dynamics in treatment of swine wastewater containing antibiotics by aerobic granular sludge[J]. Chemosphere, 2020, 260:127544.
[34] Suarez S, Lema J M, Omil F. Removal of pharmaceutical and personal care products (PPCPs) under nitrifying and denitrifying conditions[J]. Water Research, 2010, 44(10):3214-3224.
[35] Prasertkulsak S, Chiemchaisri C, Chiemchaisri W, et al. Removals of pharmaceutical compounds at different sludge particle size fractions in membrane bioreactors operated under different solid retention times[J]. Journal of Hazardous Materials, 2019, 368:124-132.
[36] Samaras V G, Stasinakis A S, Mamais D, et al. Fate of selected pharmaceuticals and synthetic endocrine dis-rupting compounds during wastewater treatment and sludge anaerobic digestion[J]. Journal of Hazardous Ma-terials, 2013, 244/245:259-267.
[37] Petrie B, McAdam E J, Hassard F, et al. Diagnostic in-vestigation of steroid estrogen removal by activated sludge at varying solids retention time[J]. Chemosphere, 2014, 113:101-108.
[38] Tadkaew N, Sivakumar M, Khan S J, et al. Effect of mixed liquor pH on the removal of trace organic contam-inants in a membrane bioreactor[J]. Bioresource Technol-ogy, 2010, 101(5):1494-1500.
[39] Cecconet D, Molognoni D, Callegari A, et al. Biological combination processes for efficient removal of pharma-ceutically active compounds from wastewater:A review and future perspectives[J]. Journal of Environmental Chemical Engineering, 2017, 5(4):3590-3603.
[40] Tadkaew N, Hai F I, McDonald J A, et al. Removal of trace organics by MBR treatment:The role of molecular properties[J]. Water Research, 2011, 45(8):2439-2451.
[41] Hacıosmanoğlu G G, Mejías C, Martín J, et al. Antibiot-ic adsorption by natural and modified clay minerals as designer adsorbents for wastewater treatment:A compre-hensive review[J]. Journal of Environmental Manage-ment, 2022, 317:115397.
[42] De la Cruz N, Giménez J, Esplugas S, et al. Degradation of 32 emergent contaminants by UV and neutral photoFenton in domestic wastewater effluent previously treat-ed by activated sludge[J]. Water Research, 2012, 46(6):1947-1957.
[43] Rostam A B, Taghizadeh M. Advanced oxidation process-es integrated by membrane reactors and bioreactors for various wastewater treatments:A critical review[J]. Jour-nal of Environmental Chemical Engineering, 2020, 8(6):104566.
[44] Titchou F E, Zazou H, Afanga H, et al. Removal of or-ganic pollutants from wastewater by advanced oxidation processes and its combination with membrane processes[J]. Chemical Engineering and Processing-Process In-tensification, 2021, 169:108631.
[45] Bolong N, Ismail A F, Salim M R, et al. A review of the effects of emerging contaminants in wastewater and op-tions for their removal[J]. Desalination, 2009, 239(1-3):229-246.
[46] 孟小燕,黄宝荣.我国新污染物治理的进展、问题及对策[J].环境保护, 2023, 51(7):9-13.
[47] Wang R, Yan Y N, Liu H, et al. Integrating data depen-dent and data independent non-target screening meth-ods for monitoring emerging contaminants in the Pearl River of Guangdong Province, China[J]. The Science of the Total Environment, 2023, 891:164445.
[48] 单菁菁.探索构建中国特色新污染物防控治理体系[J].人民论坛, 2023(4):58-61.
[49] Long Y, Song L, Shu Y Q, et al. Evaluating the spatial and temporal distribution of emerging contaminants in the Pearl River Basin for regulating purposes[J]. Ecotoxi-cology and Environmental Safety, 2023, 257:114918.
[50] Raza A, Hassan J Z, Mahmood A, et al. Recent advanc-es in membrane-enabled water desalination by 2D frameworks:Graphene and beyond[J]. Desalination, 2022, 531:115684.
[51] Chen L, Maqbool T, Nazir G, et al. Developing the large-area manganese-based catalytic ceramic mem-brane for peroxymonosulfate activation:Applications in degradation of endocrine disrupting compounds in drink-ing water[J]. Journal of Membrane Science, 2022, 655:120602.
[52] Ponce Romero J, Hallett S, Jude S. Leveraging big data tools and technologies:Addressing the challenges of the water quality sector[J]. Sustainability, 2017, 9(12):2160.
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