高介电常数介电材料在储能方面的特殊作用使其在电工、电子技术领域有着重要的应用。随着电子工业的发展,高储能密度介电材料受到越来越多的关注,出现了一些新型的高储能密度介电材料。高储能密度介电材料具有高的介电常数和击穿强度,其发展的关键是提高储能密度。本文对近年来高储能密度介电材料的研究发展进行了概述,主要讨论了通过对钛酸钡的改性(即掺杂改性、表面包覆改性和复合材料制备)来提高介电材料的储能密度。分析了钛酸钡/聚合物复合材料的制备方法及其介电性能的影响因素,其中,陶瓷填料和聚合物基体2相界面的相容性是复合材料介电性能的重要影响因素。同时,指出了解决BaTiO₃粒子在聚合物基体中的分散问题、填料和聚合物基体的选择以及制备过程中工艺条件的控制都是研究兼具高介电强度和高介电常数复合材料的发展方向。

Dielectric materials with high dielectric constant are widely used because of their excellent properties in energy storage, and play an important role in the area of electrical and electronic technologies. With the development of electronic industry, high energy density dielectric materials attract more and more attentions, and various novel dielectric materials with high energy storage density were developed. Dielectric materials with high energy storage density have high dielectric constants and high breakdown strength. It is an important issue to improve the energy storage density of dielectric materials. This paper reviews the latest development of high energy storage density dielectric materials, and discusses the modification of barium titanate to improve the energy storage density. Three approaches are adopted to achieve high electric energy density, namely, doping modification, surface coating and composite materials preparation. The main discussion is focused on the preparation of barium titanate/polymer composites, and the factors affecting dielectric properties, of which the compatibility of interface between barium titanate and polymer is of great importance. The developing direction of the composites is in the improvement of the dispersity property of particles in the polymer matrix, the selection of filling particles and polymer matrix and the control of preparation process conditions.