Progress in the preparation and application of thermo- and pH-responsive polymer membranes

JIANG Ping, WU Yiqiang

Science & Technology Review ›› 2016, Vol. 34 ›› Issue (19) : 22-30.

PDF(8643 KB)
PDF(8643 KB)
Science & Technology Review ›› 2016, Vol. 34 ›› Issue (19) : 22-30. DOI: 10.3981/j.issn.1000-7857.2016.19.002
Special lssues

Progress in the preparation and application of thermo- and pH-responsive polymer membranes

Author information -
School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China

Abstract

The environmental responsive intelligent polymer membrane has broad prospects in the fields of material separation, control and release. In this paper, the preparation methods and applications of the thermo- and pH-responsive polymer membranes are reviewed, and the construction method, the structure activity relationship and the response mechanism of the non-polar and self-support thermo- and pH-responsive polymers are discussed.

Key words

polymer intelligent membrane / thermo-responsibility / pH-responsibility

Cite this article

Download Citations
JIANG Ping, WU Yiqiang. Progress in the preparation and application of thermo- and pH-responsive polymer membranes[J]. Science & Technology Review, 2016, 34(19): 22-30 https://doi.org/10.3981/j.issn.1000-7857.2016.19.002

References

[1] Schmaljohann D.Thermo-and pH-responsive polymers in drug delivery[J].Advanced Drug Delivery Reviews,2006,58(15):1655-1670.
[2] Lokuge I,Wang X J,Bohn P W.Temperature-controlled flow switching in nanocapillary array membranes mediated by poly(N-isopropylacryl-amide) polymer brushes grafted by atom transfer radical polymerization[J].Langmuir,2007,23(1):305-311.
[3] Nakayama H,Kaetsu I,Uchida K,et al.Preparation of temperature re-sponsive fragrance release membranes by UV curing[J].Radiation Phys-ics and Chemistry,2003,67(2):131-136.
[4] Zhang K,Wu X Y.Temperature and pH-responsive polymeric compos-ite membranes for controlled delivery of proteins and peptides[J].Bioma-terials,2004,25(22):5281-5291.
[5] Yang B,Yang W T.Thermo-Sensitive switching membranes regulated by pore-covering polymer brushes[J].Journal of Membrane Science,2003,218(1-2):247-255.
[6] Xie R,Li Y,Chu L Y.Preparation of thermo-responsive gating mem-branes with controllable response temperature[J].Journal of Membrane Science,2007,289(1-2):76-85.
[7] Zhao C S,Nie S Q,Tang M,et al.Polymeric pH-sensitive membranesA review[J].Progress in Polymer Science,2011,36(11):1499-1520.
[8] Ito Y,Ochiai Y,Park Y S,et al.pH-sensitive Gating by conformational change of a polypeptide brush grafted onto a porous polymer membrane[J].Journal of American chemical society,1997,119(7):1619-1623.
[9] Wang D Q,Tan J J,Kang H L,et al.Synthesis,self-assembly and drug release behaviors of pH-responsive copolymers ethyl cellulosegraft-PDEAEMA through ATRP[J].Carbohydrate Polymers,2011,84(1):195-202.
[10] Vladimir T.Multifunctional and stimuli-sensitive pharmaceutical nano-carriers[J].European Journal of Pharmaceutics and Biopharmaceutics,2009,71(3):431-444.
[11] Park H W,Jin H S,Yang S Y,et al.Tunable phase transition behav-iors of pH-sensitive polyaspartamides having various cationic pendant groups[J].Colloid and Polymer Science,2009,287(3):919-926.
[12] Franck-Lacaze L,Sistat P,Huguet P.Determination of the pK(a) of poly(4-vinylpyridine)-based weak anion exchange membranes for the investigation of the side proton leakage[J].Journal of Membrane Sci-ence,2009,326(2):650-658.
[13] M'Bareck C O,Nguyen Q T,Alexandre S,et al.Fabrication of ion-ex-change ultrafiltration membranes for water treatment I.Semi-interpene-trating polymer networks of polysulfone and poly(acrylic acid)[J].Jour-nal of Membrane Science,2006,278(1-2):10-18.
[14] Mbareck C,Nguyen Q T,Alaoui O T,et al.Elaboration,characteriza-tion and application of polysulfone and polyacrylic acid blends as ul-trafiltration membranes for removal of some heavy metals from water[J].Journal of Hazardous Materials,2009,171(1-3):93-101.
[15] Zhang K,Huang H Y,Yang G C,et al.Characterization of nanostruc-ture of stimuli-responsive polymeric composite membranes[J].Biomac-romolecules,2004,5(4):1248-1255.
[16] Hu K,Dickson J M.Development and characterization of poly(vinyli-dene fluoride)-poly(acrylic acid) pore-filled pH-sensitive membranes[J].Journal of Membrane Science,2007,301(1-2):19-28.
[17] Hu K,Dickson J M.Modelling of the pore structure variation with pH for pore-filled pH-sensitive poly(vinylidene fluoride)-poly(acrylic ac-id) membranes[J].Journal of Membrane Science,2008,321(2):162-171.
[18] Abu Seman M N,Khayet M,Bin Ali Z I,et al.Reduction of nanofiltra-tion membrane fouling by UV-initiated graft polymerization technique[J].Journal of Membrane Science,2010,355(1-2):133-141.
[19] Shi Q,Su Y L,Ning X,et al.Graft polymerization of methacrylic acid onto polyethersulfone for potential pH-responsive membrane materials[J].Journal of Membrane Science,2010,347(1-2):62-68.
[20] He D M,Susanto H,Ulbricht M.Photo-irradiation for preparation,modification and stimulation of polymeric membranes[J].Progress in Polymer Science,2009,34(1):62-98.
[21] Li W H,Liu P B,Zou H W,et al.pH sensitive microporous polypro-pylene membrane prepared through ozone induced surface grafting[J].Polymers of Advanced Technologies,2009,20(3):251-257.
[22] Akamatsu K,Yamaguchi T.Novel preparation method for obtaining pH-responsive core-shell microcapsule reactors[J].Industrial & Engi-neering Chemistry Research,2007,46(1):124-130.
[23] Tong G S,Liu T,Zhao L,et al.Supercritical carbon dioxide-assisted preparation of polypropylene grafted acrylic acid with high grafted con-tent and small gel percent[J].The Journal of Supercritical Fluids,2009,48(3):261-268.
[24] Zhou J,Li W,Gu J S,et al.Development of a novel RAFT-UV graft-ing technique to modify polypropylene membrane used for NOM re-moval[J].Separation and Purification Technology,2010,71(2):233-240.
[25] Schepelina O,Poth N,Zharov I.pH-responsive nanoporous silica col-loidal membranes[J].Advanced Functional Materials,2010,20(12):1962-1969.
[26] Wang M,An Q F,Wu L G,et al.Preparation of pH-responsive phe-nolphthalein poly(ether sulfone) membrane by redox-graft pore-filling polymerization technique[J].Journal of Membrane Science,2007,287(2):257-263.
[27] Guo H F,Ulbricht M.Preparation of thermo-responsive polypropylene membranes via surface entrapment of poly(N-isopropylacrylamide)-containing macromolecules[J].Journal of Membrane Science,2011,372(1-2):331-339.
[28] Su M,Teoh M M,Wang K Y,et al.Effeet of inner-layer thermal con-duetivity on flux enhancement of dual-layer hollow fiber membranes in direet contact membrane distillation[J].Journal of Membrane Sci-ence,2010,364:278-289.
[29] 王闻宇.聚偏氟乙烯智能膜的制备及其性能研究[D].天津:天津工业大学,2006.Wang Wenyu.PreParation and ProPerties of Intelligent Poly(vinyli-dene fluoride) Membranes[D].Tianjin:Tianjin Polytechnic University,2006.
[30] Peinemann K V,Abetz V,Simon P F W,Asymmetric superstructure formed in a block copolymer via phase separation[J].Nature Materials,2007,6(12):992-997.
[31] Schacher F,Ulbricht M,Müller A H E.Self-supporting,double stimu-li-responsive porous membranes from polystyrene-block-poly(N,Ndimethylaminoethyl methacrylate) diblock copolymers[J].Advanced Functional Materials,2009,19(7):1040-1045.
[32] Schacher F,Rudolph T,Wieberger F,et al.Double stimuli-responsive ultrafiltration membranes from polystyrene-block poly(N,N-dimethyl-aminoethyl methacrylate) diblock copolymers[J].Applied Materials and Interfaces,2009,1(7):1492-1503.
[33] Du J,Tao C Y,He X,et al.Environmentally sensitive microfiltration membranes with pH responsive valve[J].Journal of Central South Uni-versity of Technology,2007,14(Suppl 3):472-475.
[34] Karppi J,Akerman S,Akerman K,et al.Adsorption of metal cations from aqueous solutions onto the pH responsive poly(vinylidene fluo-ride grafted poly(acrylic acid)(PVDF-PAA) membrane[J].Journal of Polymer Research,2010,17(1):71-76.
[35] Li C Y,Cao B,Wang W C,et al.pH-induced on-off switching of polycarbonate track-etched membranes by plasma-induced surface grafting[J].Polymers for Advanced Technologies,2010,21(10):698-703.
[36] Lue S J,Chen C H,Shih C M,et al.Grafting of poly(N-isopro-pylacrylamide-co-acrylic acid) on micro-porous polycarbonate films:regulating lower critical solution temperatures for drug controlled re-lease[J].Journal of Membrane Science,2011,379(1):330-340.
[37] Guo H,Ulbricht M.Surface modification of polypropylene microfiltra-tion membrane via entrapment of an amphiphilic alkyl oligoethyleneg-lycolether[J].Journal of Membrane Science,2010,349:312-320.
[38] Guo H,Ulbricht M.The effects of(macro) molecular structure on hy-drophilic surface modification of polypropylene membranes via entrap-ment[J].Journal of Colloid and Interface Science,2010,350:99-109.
[39] Berndt E,Ulbricht M.Synthesis of block copolymers for surface func-tionalization with stimuli-responsive macromolecules[J].Polymer,2009,50(22):5181-5191.
[40] Jain S,Bajpai A K.Investigation of water sorption and blood compati-ble behaviors of polyethylene glycol(PEG) plasticized membranes of poly(vinyl alcohol-g-acrylonitrile)[J].Advanced Science,Engineering and Medicine,2012,4(6):469-478.
[41] Franck-Lacaze L,Sistat P,Huguet P.Determination of the pKa of poly(4-vinylpyridine)-based weak anion exchange membranes for the investigation of the side proton leakage[J].Journal of Membrane Science,2009,326(2):650-658.
[42] Du J,Tao C Y,He X,et al.Environmentally sensitive microfiltration membranes with pH responsive valve[J].Journal of Central South Uni-versity of Technology,2007,14(Suppl 3):472-475.
[43] Liu S,Billingham N C,Armes S P.A schizophrenic water-soluble di-block copolymer[J].Angewandte Chemie International Edition,2001,40(12):2328-2331.
[44] Bousquet A,Ibarboure E,Papon E,et al.Structured multistimuli-re-sponsive functional polymer surfaces obtained by interfacial diffusion of amphiphilic block copolymers[J].Journal of Polymer Science Part A:Polymer Chemistry,2010,48(9):1952-1961.
[45] Hou J W,Shi Q,Stagnaro,P.Aqueious-based immobilization of initi-tor and surface-initiated ATRP to construct henriocompatible surface of poly(styrene-b-(ethylene-co-butylene)-b-styrene) elastome[J].Colloids and Surfaces B-Biointerfaces,2013,111:333-341.
[46] Perera D H N,Nataraj S K,Thomson N M,et al.Room-temperature development of thin film composite reverse osmosis membranes from cellulose acetate with antibacterial properties[J].Journal of Membrane Science,2014,453:212-220.
PDF(8643 KB)

Accesses

Citation

Detail

Sections
Recommended

/