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Degradation of microcrystalline cellulose catalyzed by heteropoly acid H3PW12O40 |
YUAN Yuguo1, WANG Jingyun1,2, FU Nihong1, ZANG Shuliang1,2 |
1. School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China;
2. China University of Petroleum (East China), Qingdao 266580, China |
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Abstract: Microcrystalline cellulose is degraded in 1-allyl-3-methylimidazolium chloride ([Amim]Cl) ionic liquid using heteropoly acid H3PW12O40 as catalyst under the mild environment. The effects of reaction temperature and time, the amount of catalysts and water on the degradation of cellulose have been investigated in details. When using 0.09eq of H3PW12O40, 0.07 mL of water, ca. 0.6 mmol of microcrystalline cellulose and 2.0 g of [Amim]Cl under microwave irradiation for 30 min at 160℃, 66.8% of total reducing sugar (TRS) yield, 32.8% of glucose yield and 17.6% of the cellobiose yield can be obtained.
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Received: 13 July 2015
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[1] Corma A, Iborra X, Velty A. Chemical routes for the transformation of biomass into chemicals[J]. Chemical Reviews, 2007, 107(6): 2411-2502.
[2] Tadesse H, Luque R. Advances on biomass pretreatment using ionic liquids: An overview[J]. Energy & Environmental Science, 2011, 4(10): 3913-3929.
[3] 王景芸, 刘美菊, 周明东, 等. 酸性阳离子交换树脂催化降解微晶纤维素的研究[J]. 现代化工, 2015, 35(3): 90-94. Wang Jingyun, Liu Meiju, Zhou Mingdong, et al. Cellulose degradation catalyzed by acidic cation exchange resin[J]. Modern Chemical Industry, 2015, 35(3): 90-94.
[4] 吴树昌, 王春雷, 高勇军, 等. 离子液体中微波辅助的Lewis酸催化纤维素制备5-羟甲基糠醛[J]. 催化学报, 2010, 31(9): 1157-1161. Wu Shuchang, Wang Chunlei, Gao Yongjun, et al. Production of 5-hydroxymethyifurfural from cellulose catalyzed by lewis acid under microwave irradiation in ionic liquid[J]. Chinese Journal of Catalysis, 2010, 31(9): 1157-1161.
[5] Zhou C, Xia X, Lin C, et al. Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels[J]. Chemical Society Reviews, 2011, 40 (11): 5588-5617.
[6] Swatloski R, Spear S, Holbrey J, et al. Dissolution of Cellulose with Ionic Liquids[J]. Journal of the American Chemical Society, 2002, 124(18): 4974-4975.
[7] Liu D T, Xia K F, Cai W H, et al. Investigations about dissolution of cellulose in the 1-allyl-3-alkylimidazolium chloride ionic liquids[J]. Carbohydrate Polymer, 2012, 87(2): 1058-1064.
[8] Himmel M E, Ding S Y, Johnson D K, et al. Biomass recalcitrance: engineering plants and enzymes for biofuels production[J]. Science, 2007, 315(5813): 804-807.
[9] Chheda J N, Román-Leshkov Y, Dumesic J A. Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono-and poly-saccharides[J]. Green Chemistry, 2007, 9(4): 342-350.
[10] Qi X, Watanabe M, Aida T M, et al. Catalytic conversion of cellulose into 5-hydroxymethylfurfural in high yields via a two-step process[J]. Cellulose, 2011, 18(5): 1327-1333.
[11] Zhao H, Holladay J E, Brown H, et al. Metal chlorides in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural[J]. Science, 2007, 316(5831): 1597-1600.
[12] Adsul M G, Singhvi M S, Gaikaiwari S A, et al. Development of biocatalysts for production of commodity chemicals from lignocellulosic biomass[J]. Bioresource Technology, 2011, 102(6): 4304-4312.
[13] Vo H T, Widyaya V T, Kim H S, et al. Hydrolysis of ionic cellulose to glucose[J]. Bioresource Technology, 2014, 167: 484-489.
[14] Camacho F, González-Tello P, Jurado E, et al. Microcrystalline-Cellulose Hydrolysis with Concentrated Sulphuric Acid[J]. Journal of Chemical Technology and Biotechnology, 1996, 67(4): 350-356.
[15] Vilcocq L, Castilho P C, Carvalheiro F, et al. Hydrolysis of oligosaccharides over solid acid catalysts: A review[J]. ChemSusChem, 2014, 7 (4): 1010-1019.
[16] Timofeeva M N. Acid catalysis by heteropoly acids[J]. Applied Catalysis A: General, 2003, 256(1): 19-35.
[17] Kozhevnikov I V. Sustainable heterogeneous acid catalysis by heteropoly acids[J]. Journal of Molecular Catalysis A: Chemical, 2007, 262(1): 86-92.
[18] Kozhevnikov I V. Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions[J]. Chemical Reviews, 1998, 98(1): 171-198
[19] Hu L, Lin L, Wu Z, et al. Chemocatalytic hydrolysis of cellulose into glucose over solid acid catalysts[J]. Applied Catalysis B: Environmental, 2015, 174: 225-243.
[20] Sun Z, Cheng M, Li H, et al. One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis[J]. RSC Advances, 2012, 2(24): 9058-9065.
[21] Palkovits R, Tajvidi K, Ruppert A M, et al. Heteropoly acids as efficient acid catalysts in the one-step conversion of cellulose to sugar alcohols[J]. Chemical Communications, 2011, 47(1): 576-578.
[22] Tian J, Wang J, Zhao S, et al. Hydrolysis of cellulose by the heteropoly acid H3PW12O40[J]. Cellulose, 2010, 17(3): 587-594.
[23] Zhang Z, Zhao Z K. Microwave-assisted conversion of lignocellulosic biomass into furans in ionic liquid[J]. Bioresource Technology, 2010, 101(3): 1111-1114.
[24] Miller G L. Use of DinitrosaLicyLic Acid Reagent for determination of reducing sugar[J]. Analytical Chemistry, 1959, 31(3): 426-428.
[25] Cavani F. Heteropolycompound-based catalysts: a blend of acid and oxidizing properties[J]. Catalysis Today, 1998, 41(1): 73-86.
[26] Sievers C, Valenzuela-Olarte M B, Marzizletti T, et al. Ionic-liquidphase hydrolysis of pine wood[J]. Industrial & Engineering Chemistry Research, 2009, 48(3): 1277-1286. |
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