The graphene oxide(GO) is a one-atom thick nanosheet with good hydrophilic properties and the water molecules move fast between GO layers. Adjusting the distance between GO membranes can achieve a good retention of the solute, with excellent separation performance in the water treatment. This paper reviews the preparation methods of GO-basedmembranes, including the vacuum filtration, the spray coating, the spin coating, the dip coating and the layer by layer self-assembly method. In addition, the research progress of GO-based membranes in reverse osmosis, nanofiltration and pervaporation is discussed in detail. The future applications of GO-based membranes in water treatment are discussed as well.
[1] Novoselov K, Geim A K, Morozov S, et al. Two- dimensional gas of massless dirac fermions in graphene[J]. Nature, 2005, 438 (7065): 197- 200.
[2] Li D, Müller M B, Gilje S, et al. Processable aqueous dispersions of graphene nanosheets[J]. Nature nanotechnology, 2008, 3(2): 101-105.
[3] Eda G, Fanchini G, Chhowalla M. Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J]. Nature nanotechnology, 2008, 3(5): 270-274.
[4] Huang H, Mao Y, Ying Y, et al. Salt concentration, ph and pressure controlled separation of small molecules through lamellar graphene oxide membranes[J]. Chem Commun, 2013, 49(53): 5963-5965.
[5] Han Y, Xu Z, Gao C. Ultrathin graphene nanofiltration membrane for water purification[J]. Advanced Functional Materials, 2013, 23(29): 3693-3700.
[6] Gao S J, Qin H, Liu P, et al. Swcnt-intercalated go ultrathin films for ultrafast separation of molecules[J]. Journal of Materials Chemistry A, 2015, 3(12): 6649-6654.
[7] Wang X, Zhi L, Müllen K. Transparent, conductive graphene electrodes for dye-sensitized solar cells[J]. Nano Letters, 2008, 8(1): 323-327.
[8] Kim H W, Yoon H W, Yoon S-M, et al. Selective gas transport through few-layered graphene and graphene oxide membranes[J]. Science, 2013, 342(6154): 91-95.
[9] Becerril H A, Mao J, Liu Z, et al. Evaluation of solution- processed reduced graphene oxide films as transparent conductors[J]. ACS Nano, 2008, 2(3): 463-470.
[10] Gilje S, Han S, Wang M, et al. A chemical route to graphene for device applications[J]. Nano Letters, 2007, 7(11): 3394-3398.
[11] Pham V H, Cuong T V, Hur S H, et al. Fast and simple fabrication of a large transparent chemically-converted graphene film by spray-coating[J]. Carbon, 2010, 48(7): 1945-1951.
[12] Hu M, Mi B. Enabling graphene oxide nanosheets as water separation membranes[J]. Environmental Science & Technology, 2013, 47(8): 3715- 3723.
[13] KannamSK,ToddB,HansenJS,etal.Slipflowingraphene nanochannels[J]. The Journal of Chemical Physics, 2011, 135(14): 144701.
[14] Mi B. Graphene oxide membranes for ionic and molecular sieving[J]. Science, 2014, 343(6172): 740-742.
[15] Qiu L, Zhang X, Yang W, et al. Controllable corrugation of chemically converted graphene sheets in water and potential application for nanofiltration[J]. Chem Commun, 2011, 47(20): 5810-5812.
[16] HanY,JiangY,GaoC.High-fluxgrapheneoxidenanofiltration membrane intercalated by carbon nanotubes[J]. Acs Applied Materials & Interfaces, 2015, 7(15): 8147-8155.
[17] Nair R, Wu H, Jayaram P, et al. Unimpeded permeation of water through helium-leak-tight graphene-based membranes[J]. Science, 2012, 335 (6067): 442-444.
[18] Hung W- S, An Q- F, De Guzman M, et al. Pressure- assisted selfassembly technique for fabricating composite membranes consisting of highly ordered selective laminate layers of amphiphilic graphene oxide[J]. Carbon, 2014, 68: 670-677.
[19] Tang Y P, Paul D R, Chung T S. Free-standing graphene oxide thin films assembled by a pressurized ultrafiltration method for dehydration of ethanol[J]. Journal of Membrane Science, 2014, 458: 199-208.
[20] Lou Y, Liu G, Liu S, et al. A facile way to prepare ceramic-supported graphene oxide composite membrane via silane- graft modification[J]. Applied Surface Science, 2014, 307: 631-637.
[21] Zhang J, Xu Z, Shan M, et al. Synergetic effects of oxidized carbon nanotubes and graphene oxide on fouling control and anti- fouling mechanism of polyvinylidene fluoride ultrafiltration membranes[J]. Journal of Membrane Science, 2013, 448: 81-92.
[22] Ganesh B, Isloor A M, Ismail A. Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane[J]. Desalination, 2013, 313: 199-207.
[23] Wang Z, Yu H, Xia J, et al. Novel go-blended pvdf ultrafiltration membranes[J]. Desalination, 2012, 299: 50-54.
[24] Zhang J, Xu Z, Mai W, et al. Improved hydrophilicity, permeability, antifouling and mechanical performance of pvdf composite ultrafiltration membranes tailored by oxidized low-dimensional carbon nanomaterials[J]. Journal of Materials Chemistry A, 2013, 1(9): 3101-3111.