Characterization and analysis of preservative paper made by activated carbon loaded by potassium permanganate

  • WANG Haili ,
  • XIAO Shengling ,
  • YUE Jinquan ,
  • LIU Yinxin
  • 1. Engineering Technology Department, Northeast Forestry University, Harbin 150040, China;
    2. Material Science and Engineering Department, Northeast Forestry University, Harbin 150040, China

Received date: 2015-05-06

  Revised date: 2015-06-16

  Online published: 2015-12-15


Preservative is made by modified activated carbon which contains potassium permanganate, the paper is used as carrier, and the preservative paper is developed by the method of putting preservatives into pulp. Analytical methods such as the infrared spectrum (FTIR), the X ray diffraction (XRD), the thermogravimetric analysis (TGA) and the scanning electron microscope (SEM) are used to study the structures of the preservative and the preservative paper. The FTIR analysis shows that the activated carbon loaded with the saturated potassium permanganate contains more oxygen functional groups on the surface, the combination of the antistaling agent and the paper serves as the physical bond. The XRD analysis shows that the potassium permanganate could destroy the crystal structure of the activated carbon, the crystallization degree of the preservative paper is decreased after the antistaling agent is added. From the TGA curve, it is seen that the temperature of the thermal decomposition of the fresh paper is lower than that of the control group, which is due to the decrease of the crystallinity of the preservative paper. The result of the SEM test shows that the antistaling agent could make the preservative paper surface coarse.

Cite this article

WANG Haili , XIAO Shengling , YUE Jinquan , LIU Yinxin . Characterization and analysis of preservative paper made by activated carbon loaded by potassium permanganate[J]. Science & Technology Review, 2015 , 33(22) : 45 -49 . DOI: 10.3981/j.issn.1000-7857.2015.22.006


[1] 孟冠华, 李爱民, 张全兴. 活性炭的表面含氧官能团及其对吸附影响 的研究进展[J]. 离子交换与吸附, 2007, 23(1): 88-94. Meng Guanhua, Li Aimin, Zhang Quanxing. Studies on the oxygencontaining groups of activated carbon and their effects on the adsorption character[J]. Ion Exchange and Adsorption, 2007, 23(1): 88- 94.
[2] 张世润, 胡蜂. 活性炭工艺学[M]. 哈尔滨: 东北林业大学出版社, 2002. Zhang Shirun, Hu Feng. Activated carbon technology[M]. Harbin: Northeast Forestry University Press, 2002.
[3] 郭福阳. 果蔬采后保鲜剂的研究与应用[D]. 乌鲁木齐: 新疆大学, 2010. Guo Fuyang. Study on Application of preservatives for postharvest fruits and vegetables[D]. Urumqi: Xinjiang University, 2010.
[4] 卢敬科. 改性活性炭的制备及其吸附重金属性能的研究[D]. 杭州: 浙 江工业大学, 2009. Lu Jingke. Study on the preparation of modified activated carbon and its adsorption of heavy metals[D]. Hangzhou: Zhejiang University of Technology, 2009.
[5] 曹翠翠. 高锰酸钾改性颗粒活性炭处理苯酚废水的试验研究[D]. 大 连: 大连海事大学, 2010. Cao Cuicui. The study on treating phenol wastewater by modified granular activated carbon with potassium permanganate[D]. Dalian: Dalian Maritime University, 2010.
[6] 刘银鑫, 肖生苓, 姚培培, 等. 活性炭基保鲜纸的研制及其保鲜效果研 究[J]. 食品工业科技, 2014, 21: 337-340. Liu Yinxin, Xiao Shengling, Yao Peipei, et al. Development of activated carbon preservative paper and research of its preservative effect[J]. Science and Technology of Food Industry, 2014, 21: 337-340.
[7] Zhou A, Ma X, Song C. Effects of oxidative modification of carbon surface on the adsorption of sulfur compounds in diesel fuel[J]. Applied Catalysis B: Environmental, 2009, 87(3): 190-199.
[8] 林燕. 适合果蔬流通高效乙烯脱除剂的研究及其应用[D]. 天津: 天津 科技大学, 2010. Lin Yan. Reaearch and application on efficient ethylene removal agent which is fit for fruit and veaetables distribution[D]. Tianjin: University of Science and Technology of Tianjin, 2010.
[9] 王晓卉, 俞亭超. 高锰酸钾改性活性炭对水中Sb(III)的吸附[J]. 浙江 大学学报: 工学版, 2012, 46(11): 2028-2034. Wang Xiaohui, Yu Tingchao. The adsorption of Sb (III)in aqueous by KMnO4- modified activated carbon[J]. 2012, 46(11): 2028- 2034[J]. Journal of Zhejiang University: Engineering Science, 2012, 46(11): 2028-2034.
[10] Zielke U, Hüttinger K J, Hoffman W P. Surface-oxidized carbon fibers: I. Surface structure and chemistry[J]. Carbon, 1996, 34(8): 983- 998.
[11] El-Hendawy A N A. Influence of HNO3 oxidation on the structure and adsorptive properties of corncob- based activated carbon[J]. Carbon, 2003, 41(4): 713-722.
[12] 李生娟, 王树林. 氧化铋掺杂纳米二氧化锰/活性炭复合电极[J]. 化 工学报, 2008, 59(2): 514-519. Li Shengjuan, Wang Shulin. Nano-bismuth oxide doped MnO2/nanoactived carbon as composite electrode materials[J]. Journal of Chemical Industry and Engineering, 2008, 59(2): 514-519.
[13] 符韵林, 赵广杰. 二氧化硅/木材复合材料的微观结构与物理性能[J]. 复合材料学报, 2006, 24(4): 52-59. Fu Yunlin, Zhao Guangjie. Microstructure and physical properties of silicon dioxide/wood composite[J]. Acta Materiae Compositae Sinica, 2006, 24(4): 52-59.
[14] 邹萍萍. 聚乳酸/纳米纤维素可降解食品包装材料的制备与发泡研究[D]. 杭州: 浙江大学, 2013. Zou Pingping.Preparation and foaming of PLA- based biodegradable food package material reinforced by NCC[D]. Hangzhou: Zhejiang Univeraity, 2013.
[15] Yu C, Qiu J S, Sun Y F, et al. Adsorption removal of thiophene and dibenzothiophene from oils with activated carbon as adsorbent: effect of surface chemistry[J]. Journal of Porous Materials, 2008, 15(2): 151-157.