Progresses of phase equilibria and thermodynamics of the plateau lithium-containing brine systems

LI Long; GUO Yafei; ZHANG Sisi; DENG Tianlong

doi:10.3981/j.issn.1000-7857.2017.12.008

Science & Technology Review >

2017 , Vol. 35 >Issue 12: 55 - 61

DOI: https://doi.org/10.3981/j.issn.1000-7857.2017.12.008

Articles

Progresses of phase equilibria and thermodynamics of the plateau lithium-containing brine systems

LI Long ,
GUO Yafei ,
ZHANG Sisi ,
DENG Tianlong

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1. Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Material Sciences, Tianjin University of Science and Technology, Tianjin 300457, China;
2. College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Received date: 2016-11-24

Revised date: 2016-12-10

Online published: 2017-07-03

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Abstract

Salt lakes in the Qinghai-Tibetan Plateau in the western China are famous for their high concentration of the lithium ion.The major chemical composition of brines can be expressed as the complex brine system of Li⁺,Na⁺,K⁺,Mg²⁺//Cl^-,SO₄^2-,CO₂^3-,borate-H₂O.Studies of the phase equilibria and thermodynamics of salt-water systems are of great significance either for the comprehensive utilization of brine resources or for the understanding of the genesis,the metallogenic process and the chemical behavior of these brines.In this paper,the stable and metastable phase equilibria of lithium-containing salt-water systems and thermodynamics of several lithium salts and their aqueous solutions are reviewed.And the problems at the present and the new trends in the future are discussed.

Key words： salt lake brine system; phase equilibria; thermodynamics; lithium salts

Cite this article

LI Long , GUO Yafei , ZHANG Sisi , DENG Tianlong . Progresses of phase equilibria and thermodynamics of the plateau lithium-containing brine systems[J]. Science & Technology Review, 2017 , 35(12) : 55 -61 . DOI: 10.3981/j.issn.1000-7857.2017.12.008

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