Science & Technology Review >

2024 , Vol. 42 >Issue 4: 31 - 39

DOI: https://doi.org/10.3981/j.issn.1000-7857.2024.04.003

Exclusive：Eco-materials and Evaluation Technology

Research progress of ionic liquids screening for gases captnre and separation by COSMO-RS method

  • JIAO Mengqing ,
  • ZHANG Ruixue ,
  • QI Letian ,
  • ZHAO Nan
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  • 1. Hebei Center for Ecological and Environmental Geology Research, Hebei GEO University, Shijiazhuang 050031, China;
    2. State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology(Shandong Academy of Sciences), Jinan 250300, China

Received date: 2023-02-27

  Revised date: 2023-07-28

  Online published: 2024-04-08

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Abstract

With many unique physical and chemical properties, ionic liquids are regarded as excellent substitutes of traditional solvents for adsorption and separation of gases. The predictive molecular thermodynamic model COSMO-RS(Conductor-like screening model for real solvents)can be used for modeling of the system(gas + ILs) and prediction of the gas solubility and selectivity in ILs. The review introduces the key parameters of the COSMO-RS model. The pseudo ternary system for the properties calculation of ILs used by COSMO-RS was illustrated. The research progresses for the modeling of adsorption and separation of CO2, SO2, aromatic volatile organic compounds, aliphatic volatile organic compounds, and H2O used by ILs were summarized. The correction and optimization of COSMO-RS model for ILs was discussed. Finally, the research direction of COSMO-RS model of ILs screening used for gases capture and separation is prospected.

Key words： ionic liquids; gas; COSMO-RS; adsorption; separation

Cite this article

JIAO Mengqing , ZHANG Ruixue , QI Letian , ZHAO Nan . Research progress of ionic liquids screening for gases captnre and separation by COSMO-RS method[J]. Science & Technology Review, 2024 , 42(4) : 31 -39 . DOI: 10.3981/j.issn.1000-7857.2024.04.003

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